19072-87-8Relevant articles and documents
Development of a one-stage synthesis of 2,6-di-tert-4-ethylbutylphenol from 2,6-di-tert-butylphenol
Krysin,Pokrovskii
experimental part, p. 1728 - 1733 (2009/02/06)
Investigation of the catalyzed reaction of 2,6-di-tert-butylphenol with ethanol, ethylene glycol, oligomeric glycols, and paraldehyde in a strongly basic medium permitted to develop a technologically suitable procedure for manufacture of 2,6-di-tert-4-ethyl-butylphenol, used in the synthesis of Antioxidant-425.
Oxidation of Bisphenols. II. Some Compounds Related to Galvinoxyl
Colegate, Steven M.,Hewgill, F. Richmond
, p. 351 - 369 (2007/10/02)
The oxidation of a series of 4,4'-alkylidenebis(2,6-di-t-butylphenols) having increasing substitution of the central methylene carbon by alkyl groups is examined.In the monosubstituted compounds the stability of the monophenoxy radical increases with increase in the size of the substituent, while the stability of the galvinoxyl type radical decreases. β-Coupled products are only obtained from the ethylidene bisphenol, a result that can be correlated with e.s.r. hyperfine splitting constants.With increasing mono- or di-substitution bisspiroperoxides become the preferred oxidation products.The e.s.r. spectrum of an ethylenebisgalvinoxyl biradical is described