19091-08-8

Basic information

• Product Name: Cyclohexanecarboxylic acid, 4-(1,1-dimethylethyl)-, methyl ester
• CAS NO: 19091-08-8
• Molecular Formula: C12H22O2
• Molecular Weight: 198.305
• Mol File: 19091-08-8.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: Cyclohexanecarboxylic acid, 4-(1,1-dimethylethyl)-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanecarboxylic acid, 4-(1,1-dimethylethyl)-, methyl ester(19091-08-8)
• EPA Substance Registry System: Cyclohexanecarboxylic acid, 4-(1,1-dimethylethyl)-, methyl ester(19091-08-8)

Safety Data

• Hazardous Substances Data: 19091-08-8(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 5451-55-8 4-tert-butylcyclohexanecarboxylic acid 
• 22173-19-9 4-tert-butyl-1-cyclohexene-1-carboxylic acid methyl ester 
• 74542-25-9 Dimethyl 4-tert-Butyl-1,1-cyclohexanedicarboxylate 
• 98-73-7 4-(1,1-dimethylethyl)benzoic acid 
• 5781-53-3 monomethyl oxalyl chloride 
• 85592-89-8 1-(tert-butyl)-4-iodocyclohexane 
• 34410-04-3 2-lithio-2-trimethylsilyl-1,3-dithiane 
• 98-53-3 4-tercbutyl-cyclohexanone 

Downstream Products

• 42829-54-9 Methyl 1-methyl-trans-4-tert-butylcyclohexanecarboxylate 
• 42829-53-8 Methyl 1-methyl-cis-4-tert-butylcyclohexanecarboxylate 
• 88626-86-2 methyl ester of cis-4-tert-butylcyclohexaneselenocarboxylic acid 
• 31752-57-5 1-Methyl-cis-4-tert-butylcyclohexanecarboxylic acid 
• 27069-57-4 1-Methyl-trans-4-tert-butylcyclohexanecarboxylic acid 
• 91704-32-4 trans allyl-1 hydroxymethyl-1 tertiobutyl-4 cyclohexane 
• 91704-31-3 cis allyl-1 hydroxymethyl-1 tertiobutyl-4 cyclohexane 
• 91704-59-5 cis hydroxymethyl-1 tertiobutyl-4 α,α-dimethyl-cyclohexane-ethanol 
• 91704-57-3 cis hydroxymethyl-1 tertiobutyl-4 α-methyl-cyclohexane-ethanol 
• 344442-69-9 acide (methyl-2 propene-2 yl)-1 tertiobutyl-4 cyclohexanecarboxylique 
• 344558-74-3 acide allyl-1 tertiobutyl-4 cyclohexanecarboxylique 
• 105746-46-1 N-[(trans-4-t-Butylcyclohexyl)carbonyl]-D-phenylalanine 

Relevant articles and documents

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Lipase-mediated kinetic separation of a diastereomeric mixture of 4-tert-butylcyclohexanemethanol

Diastereomerically pure trans- and cis-4-tert-butylcyclohexanemethanols have been obtained by kinetic acylation of the diastereomeric alcohol in an organic medium and by kinetic deacylation of the diastereomeric acetate in an aqueous medium both in the presence of the same lipase (lipase PS, Pseudomonas sp., Amano). The reactions take place preferentially with the trans-isomers both in organic and aqueous media to give the trans-acetate with recovery of the cis-alcohol on acylation in an organic medium,and the trans-alcohol with recovery of the cis-acetate on deacylation in an aqueous medium.