19096-89-0Relevant articles and documents
Antimalarial effect of 3-methoxy-1,2-dioxetanes on the erythrocytic cycle of Plasmodium falciparum
Lopes, Nicolas S.,Yoshitake, Ariane M.,Silva, Adriana F.,Oliveira, Vani X.,Silva, Leandro S.,Pinheiro, Ana A. S.,Ciscato, Luiz Francisco M. L.
, p. 1373 - 1377 (2015)
The antimalarial activity of peroxides most likely originates from their interaction with iron(II) species located inside the malaria parasite, which forms destructive radical species through a Fenton-like mechanism. This article reports the first evaluat
Practical preparation of methyl vinyl ethers through the direct coupling of ketones with CHCl2OMe promoted by Mg/TiCl4/THF
Ananthan, Bakthavachalam,Yan, Tu-Hsin
supporting information, p. 753 - 760 (2018/03/12)
Herein we utilized a new methylene carbenoid as an extremely simple and highly practical reagent for the preparation of vinyl ether with good to excellent yield. This method efficiently effects methoxymethylenation or vinyl ether formation of enolizable, nonenolizable, and sterically hindered ketones. The complexation of Ti–Mg–CHOMe was facilitated, presumably, by THF dramatically increasing the feasibility; and scope of this protocol is to produce vinyl ethers which can be used as convenient building blocks for the preparation of biologically useful molecules.
Silica-immobilized chiral dirhodium(II) catalyst for enantioselective carbenoid reactions
Chepiga, Kathryn M.,Feng, Yan,Brunelli, Nicholas A.,Jones, Christopher W.,Davies, Huw M. L.
supporting information, p. 6136 - 6139 (2014/01/17)
A silica-supported dirhodium(II) tetraprolinate catalyst was synthesized in four steps from l-proline and used in a range of enantioselective transformations of donor/acceptor carbenoids. These include cyclopropenation, cyclopropanation, tandem ylide form
