191109-68-9Relevant articles and documents
Characterization and synthesis of (-)-7-methoxydodec-4(E)-enoic acid, a novel fatty acid isolated from Lyngbya majuscula
Mesguiche, Veronique,Valls, Robert,Piovetti, Louis,Peiffer, Gilbert
, p. 7473 - 7476 (1999)
The isolation and characterization of (-)-7-methoxydodec-4(E)-enoic acid, a novel fatty acid isolated from the marine Cyanophyte Lyngbya majuscula collected off the French Mediterranean coast are described. The synthesis of this acid and three of its isomers is reported.
Redox-neutral atom-economic rhodium-catalyzed coupling of terminal alkynes with carboxylic acids toward branched allylic esters
Lumbroso, Alexandre,Koschker, Philipp,Vautravers, Nicolas R.,Breit, Bernhard
supporting information; experimental part, p. 2386 - 2389 (2011/05/04)
A new method for the preparation of a wide range of branched allylic esters from terminal alkynes that proceeds via a redox-neutral propargylic CH activation employing a rhodium(I)/DPEphos catalyst is reported.
The Asymmetric Kharasch Reaction. Catalytic Enantioselective Allylic Acyloxylation of Olefins with Chiral Copper(I) Complexes and tert-Butyl Perbenzoate
Andrus, Merritt B.,Argade, Ankush B.,Chen, Xi,Pamment, Michael G.
, p. 2945 - 2948 (2007/10/02)
Olefins were treated with tert-butyl perbenzoate in the presence of chiral copper(I) triflate bisoxazoline complexes to give non-racemic allyl benzoates as products.The yields range from 34 to 62percent and the enantiometric excess from 30 to 81percent.A
