191273-68-4

Basic information

• Product Name: Benzonitrile, 4-[(dimethylhydrazono)methyl]-
• CAS NO: 191273-68-4
• Molecular Formula: C10H11N3
• Molecular Weight: 173.217
• Mol File: 191273-68-4.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Benzonitrile, 4-[(dimethylhydrazono)methyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzonitrile, 4-[(dimethylhydrazono)methyl]-(191273-68-4)
• EPA Substance Registry System: Benzonitrile, 4-[(dimethylhydrazono)methyl]-(191273-68-4)

Safety Data

• Hazardous Substances Data: 191273-68-4(Hazardous Substances Data)

Upstream product

• 55484-54-3 N’,N’-dimethylhydrazine hydrochloride 
• 105-07-7 4-cyanobenzaldehyde 
• 20114-65-2 1,4-benzenedicarboxaldehyde bis(dimethylhydrazone) 
• 57-14-7 N,N-Dimethylhydrazine 

Downstream Products

• 623-26-7 terephthalonitrile 

Relevant articles and documents

SUBSTITUTED TRIFLUOROMETHYLOXADIAZOLES FOR COMBATING PHYTOPATHOGENIC FUNGI

Substituted trifluoromethyloxadiazoles for combating phytopathogenic fungi The present invention relates to trifluoromethyloxadiazolesof the formula I, or the N-oxides, or theagriculturally useful salts thereof, and the use thereof for controlling phytopa

Hydrazone as the directing group for Ir-catalyzed arene diborylations and sequential functionalizations

The use of hemilabile pyridine-hydrazone N,N-ligands allows the highly selective Ir-catalyzed ortho,ortho'-directed diborylation of aromatic N,N-dimethylhydrazones in near-quantitative yields. One-pot sequential Suzuki-Miyaura cross-coupling with different aryl bromides provides a short entry to unsymmetrically substituted 2,6-diarylbenzaldehyde derivatives.

Hydrogen peroxide oxidation of N,N-dimethylhydrazones promoted by selenium compounds, titanosilicalites or acetonitrile

Hydrogen peroxide oxidation of N,N-dimethylhydrazones 1 promoted by title reagents has been investigated. Depending on the substrate nitrile 2 and/or amide 3 accompanied with carboxylic acid 4 and parent carbonyl compounds 5 were obtained. Formation of nitriles 2 with H2O2-acetonitrile system is limited for a few more active substrates. The mechanism of the reaction, based on generated in situ peroxyiminoacetic acid, is presented. A broad spectrum of aliphatic, unsaturated and aromatic nitriles 2 was obtained by oxidation of corresponding N,N-dimethylhydrazones 1 with hydrogen peroxide in the presence of poly(bis-9,10-anthracenyl) diselenide (PADS) (7) as catalyst.