19214-95-0

Basic information

• Product Name: (^2-₂H)propan-2-(2H)ol
• Synonyms: (^2-₂H)propan-2-(2H)ol
• CAS NO: 19214-95-0
• Molecular Weight: 62.08
• Mol File: 19214-95-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (^2-₂H)propan-2-(2H)ol(CAS DataBase Reference)
• NIST Chemistry Reference: (^2-₂H)propan-2-(2H)ol(19214-95-0)
• EPA Substance Registry System: (^2-₂H)propan-2-(2H)ol(19214-95-0)

Safety Data

• Hazardous Substances Data: 19214-95-0(Hazardous Substances Data)

Upstream product

• 67-64-1 acetone 

Downstream Products

• 4067-80-5 2-bromo-2-deuteriopropane 
• 114165-54-7 p-toluenesulfonic-2-d-isopropyl ester 

Relevant articles and documents

Combined Deuterium Nuclear Magnetic Resonance and Mass-spectrometric Studies of the Exchange Reactions of Ketones over Supported Metal Catalysts

Deuterium NMR spectroscopy has been used in conjunction with mass spectrometry to study the exchange reaction of the ketones acetone, butan-2-one and cyclopentanone over a variety of supported metal catalysts.In many of the experiments simple, random, stepwise exchange was prevalent.However, in certain instances multiple exchange occurred.For butan-2-one and cyclopentanone this multiple exchange was essentially limited to the protons on carbon atoms adjacent ot the carbonyl group, while for acetone a strong preference towards exchange into only a single methyl groupwas noted.Some hydrogenation to propan-2-ol accompanied the multiple exchange of acetone, with the majority of the alcohol being formed by addition of D2 across the carbon oxygen double bond without simultaneous exchange into the methyl group, suggesting independent η1 and η2 adsorbed acetone surface intermediates for the exchange and hydrogenation reactions respectively.