19217-54-0

Basic information

• Product Name: Cycloheptene, 3-phenyl-
• CAS NO: 19217-54-0
• Molecular Formula: C13H16
• Molecular Weight: 172.27
• Mol File: 19217-54-0.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: Cycloheptene, 3-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Cycloheptene, 3-phenyl-(19217-54-0)
• EPA Substance Registry System: Cycloheptene, 3-phenyl-(19217-54-0)

Safety Data

• Hazardous Substances Data: 19217-54-0(Hazardous Substances Data)

Upstream product

• 938-81-8 N-nitrosoacetanilide 
• 628-92-2 Cycloheptene 
• 591-50-4 iodobenzene 
• 88284-48-4 2-(trimethylsilyl)phenyl trifluoromethanesulfonate 
• 100-58-3 phenylmagnesium bromide 
• 872092-11-0 cyclohepten-1-en-3-yl diethyl phosphate 
• 5123-13-7 5,5-dimethyl-2-phenyl-1,3,2-dioxaborinane 
• 74395-08-7 3-phenylcycloheptanone 
• 1121-66-0 2-Cyclohepten-1-one 
• 36291-49-3 3-bromocycloheptene 
• 19217-56-2 3-Phenyl-cycloheptanol 
• 14922-16-8 phenylazo phenyl sulfone 
• 62-53-3 aniline 
• 2415-82-9 1-phenylbicyclo[4.1.0]heptane 

Relevant articles and documents

Alder-ene reaction of aryne with olefins

A novel intermolecular Alder-ene reaction based on aryne and olefins was developed. We performed this transformation under mild conditions such as at room temperature, and this reaction displayed high selectivity and good yields only in the presence of CsF. Hence, the intermolecular Alder-ene reaction of aryne with olefins provides an effective route to synthesize derivatives of olefins.

Copper-catalyzed γ-selective and stereospecific allyl-aryl coupling between (Z)-acyclic and cyclic allylic phosphates and arylboronates

A Cu-catalyzed allyl-aryl coupling reaction between (Z)-acyclic or cyclic allylic phosphates and arylboronates proceeds with excellent γ-E-selectivity and 1,3-anti chirality transfer, which gives the corresponding coupling products with benzylic and allylic stereogenic centers. The wide availability and easy-to-handle nature of arylboronates, the inexpensiveness of the Cu catalyst system, and the high regio- and stereoselectivities are attractive features of this protocol.

Tailoring aqueous solvents for organic reactions: Heck coupling reactions in high temperature water

High temperature water is demonstrated to be an effective solvent for Heck coupling reactions of aromatic halides with cyclic alkenes without the addition of co-solvents or specialized ligands. Reactions in the presence of LiCl and quaternary ammonium salts indicate that the reaction takes place in the aqueous phase.