1923-01-9Relevant articles and documents
1-(Trimethylsilyl)vinyl MIDA Boronate: A Trifunctional C 2 Building Block
Ivon, Yevhen M.,Voitenko, Zoya V.,Grygorenko, Oleksandr O.
, p. 1857 - 1861 (2018)
1-(Trimethylsilyl)vinyl MIDA boronate - a trifunctional C 2 building block - is prepared in only two laboratory steps and 54% overall yield starting from readily available trimethyl(vinyl)silane. The title compound undergoes orthogonal functionalization at either of the groups present in its structure, for example, iodination at the trimethylsilyl moiety, epoxidation at the double bond, and Suzuki-Miyaura coupling at the MIDA boronate.
Preparation of Functionalized Acylsilanes by Diol Cleavage of Cyclic 1,2-Dihydroxysilanes
Zimdars, Patrick,B?hlig, Kristin,Metz, Peter
, p. 6163 - 6167 (2019/08/20)
We report a study on diol cleavage of cyclic 1,2-dihydroxysilanes for the preparation of functionalized acylsilanes. Sodium periodate turned out to be an efficient reagent for this transformation, resulting in good to excellent yields. The method is chara
Preparation of Optically Active cis-Cyclopropane Carboxylates: Cyclopropanation of α-Silyl Stryenes with Aryldiazoacetates and Desilylation of the Resulting Silyl Cyclopropanes
Su, Yan,Li, Qing-Fang,Zhao, Yu-Ming,Gu, Peiming
supporting information, p. 4356 - 4359 (2016/11/13)
Optically active cis-cyclopropane carboxylates are prepared via the Rh2(S-PTAD)4-catalyzed cyclopropanation of α-silyl styrenes with aryl diazoacetates followed by desilylation of the resulting silyl cyclopropane carboxylates. The co