19247-97-3Relevant articles and documents
Unraveling the structure and exciton coupling for multichromophoric merocyanine dye molecules
Koch, Federico,Stolte, Matthias,Zitzler-Kunkel, André,Bialas, David,Steinbacher, Andreas,Brixner, Tobias,Würthner, Frank
, p. 6368 - 6378 (2017)
The relative orientation of chromophores is a key factor in determining the relationship between the structure and the functionality in molecular multichromophore ensembles. In the case of structurally flexible molecular systems in solution, the task to c
Synthesis of 1,4-Dicarbonyl Compounds from Silyl Enol Ethers and Bromocarbonyls, Catalyzed by an Organic Dye under Visible-Light Irradiation with Perfect Selectivity for the Halide Moiety over the Carbonyl Group
Esumi, Naoto,Suzuki, Kensuke,Nishimoto, Yoshihiro,Yasuda, Makoto
supporting information, p. 5704 - 5707 (2016/11/17)
We report the visible-light-induced radical coupling reaction of silyl enol ethers with α-bromocarbonyl compounds to give 1,4-dicarbonyls. The reaction was effectively accelerated using an inexpensive organic dye (eosin Y) as a photoredox catalyst. 1,4-Dicarbonyl compounds alone were afforded, without the generation of carbonyl adducts of the α-halocarbonyls, which are usually generated in the presence of fluoride anions or Lewis acids. A variety of silyl enol ethers, α-bromoketones, α-bromoesters, and α-bromoamides were applied to this system to produce the coupling compounds.
Anion receptors containing thiazine-1,1-dioxide heterocycles as hydrogen bond donors
Wang, Hong-Bo,Wisner, James A.,Jennings, Michael C.
scheme or table, (2010/08/20)
The synthesis, X-ray crystal structures and anion recognition properties of two receptors containing thiazine-1,1-dioxide heterocycles as hydrogen bond donating subunits are reported. The newly synthesized receptors display much different anion selectivit