192656-07-8

Basic information

• Product Name: RuCl(CHCHC(CH₃)2OH)(CO)(P(C₆H₅)3)2
• CAS NO: 192656-07-8
• Molecular Weight: 774.241
• Mol File: 192656-07-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: RuCl(CHCHC(CH₃)2OH)(CO)(P(C₆H₅)3)2(CAS DataBase Reference)
• NIST Chemistry Reference: RuCl(CHCHC(CH₃)2OH)(CO)(P(C₆H₅)3)2(192656-07-8)
• EPA Substance Registry System: RuCl(CHCHC(CH₃)2OH)(CO)(P(C₆H₅)3)2(192656-07-8)

Safety Data

• Hazardous Substances Data: 192656-07-8(Hazardous Substances Data)

Upstream product

• 157072-60-1 (carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II) 
• 115-19-5 2-methyl-but-3-yn-2-ol 

Relevant articles and documents

Control of intramolecular acetate-allenylidene coupling by spectator co-ligand π-acidity

The reactions of [RuHX(PPh3)3] (X = Cl, O2CMe) and [MHCl(CO)(PPh3)3] (M = Ru, Os) with 1,1-diphenylprop-2-yn-1-ol provide convenient access to alkynyl, alkenyl, propenylidene, and acetoxyallenyl complexes of divalent ruthenium and osmium, including [RuCl2(=CHCH= CPh2)(PPh3)2] and the complexes [Ru(C=CCPh2OH)-(O2CMe)(CA)2(PPh 3)2] (A = NCMe3, O), protonation (HPF6) of which provides [Ru(O2CMe)(=C=C=CPh2)-(CNCMe3) 2(PPh3)2]PF6 or the metallacycle [Ru{κ2C,O-C(=C=CPh2)O2CMe}(CO) 2(PPh3)2]PF6, respectively.