192809-59-9

Basic information

• Product Name: Silane, (1,1-dimethylethyl)[2-(2-iodoethenyl)-5,6-dimethoxy-3-methylphenoxy]di methyl-, (E)-
• CAS NO: 192809-59-9
• Molecular Formula: C17H27IO3Si
• Molecular Weight: 434.39
• Mol File: 192809-59-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Silane, (1,1-dimethylethyl)[2-(2-iodoethenyl)-5,6-dimethoxy-3-methylphenoxy]di methyl-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, (1,1-dimethylethyl)[2-(2-iodoethenyl)-5,6-dimethoxy-3-methylphenoxy]di methyl-, (E)-(192809-59-9)
• EPA Substance Registry System: Silane, (1,1-dimethylethyl)[2-(2-iodoethenyl)-5,6-dimethoxy-3-methylphenoxy]di methyl-, (E)-(192809-59-9)

Safety Data

• Hazardous Substances Data: 192809-59-9(Hazardous Substances Data)

Upstream product

• 22383-86-4 2-hydroxy-3,4-dimethoxy-6-methylbenzaldehyde 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 3020-28-8 (iodomethyl)triphenylphosphonium iodide 
• 192809-57-7 2-(tert-Butyl-dimethyl-silanyloxy)-3,4-dimethoxy-6-methyl-benzaldehyde 

Downstream Products

• 192809-62-4 (E)-1-(6-acetoxy-5,6-dimethoxy-3-methyl-1-oxocyclohexa-2,4-dien-2-yl)-2-(6-acetoxy-6-methoxy-1-oxocyclohexa-2,4-dien-3-yl)ethene 
• 192809-61-3 3-(tert-Butyl-dimethyl-silanyloxy)-2-{(E)-2-[3-(tert-butyl-dimethyl-silanyloxy)-4-methoxy-phenyl]-vinyl}-4,5-dimethoxy-1-methyl-benzene 

Relevant articles and documents

Cyclization pathways of a (Z)-stilbene-derived bis(orthoquinone monoketal)

Lead tetraacetate mediated oxidation of a (Z)-bisphenolic stilbene derivative affords a bis(orthoquinone monoketal) product. Thermolysis studies of this highly unsaturated dione reveal that sigmatropic hydrogen shifts, followed by either of two distinct solvolytic ring closures, constitute the predominate reaction pathways under heating. No evidence for a desired 6π electron electrocyclization was forthcoming.