192820-30-7Relevant articles and documents
Studies on Synthetic and Structural Aspects of Unsymmetrical Tetraorganoarsonium and stibonium Halides, Pseudohalides and Carboxylates : Electrophilic Cleavage of M-Allyl Bond
Singh Raizada, Meenu,Srivastava
, p. 646 - 649 (2008/10/09)
Triphenylarsine and triphenylstibine react with allyl bromide to give the corresponding allyltriphenylarsonium and stibonium laclides. The metal-allyl bond is readily cleaved by electrophiles, such as Br2, I2, ICI and IBr. Metathetical reactions involving allyltriphenytarsonium and stibonium halides and the appropriate metal salts, M'X(M' = Na, K, Ag; X = NCS, NCO, N3, CH3COCO, CCl3COO, C6H5COO) have been employed to yield a series of new compounds. The compounds are monomeric in beazine solution and 1 : 1 electrolyte in nitromethane.