193222-76-3

Basic information

• Product Name: Ru(NC₅H₄)4NC₅H₃CH₃NC₅H₃(CH₂)N(NC₅H₄)2NCH₃(CH₂)4MnCl₂⁽²⁺⁾
• Synonyms: Ru(NC₅H₄)4NC₅H₃CH₃NC₅H₃(CH₂)N(NC₅H₄)2NCH₃(CH₂)4MnCl₂⁽²⁺⁾
• CAS NO: 193222-76-3
• Molecular Weight: 977.863
• Mol File: 193222-76-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Ru(NC₅H₄)4NC₅H₃CH₃NC₅H₃(CH₂)N(NC₅H₄)2NCH₃(CH₂)4MnCl₂⁽²⁺⁾(CAS DataBase Reference)
• NIST Chemistry Reference: Ru(NC₅H₄)4NC₅H₃CH₃NC₅H₃(CH₂)N(NC₅H₄)2NCH₃(CH₂)4MnCl₂⁽²⁺⁾(193222-76-3)
• EPA Substance Registry System: Ru(NC₅H₄)4NC₅H₃CH₃NC₅H₃(CH₂)N(NC₅H₄)2NCH₃(CH₂)4MnCl₂⁽²⁺⁾(193222-76-3)

Safety Data

• Hazardous Substances Data: 193222-76-3(Hazardous Substances Data)

Upstream product

• 26985-31-9 methyl viologen cation radical 

Relevant articles and documents

Mimicking photosystem II reactions in artificial photosynthesis

The paper describes a project aiming at the construction of functional mimics of the oxygen evolving complex of Photosystem II, coupled to photoinduced charge separation. Biomimetic electron donors -manganese complexes and tyrosine -have been linked to a Ru(II)-polypyridine photosensitizer. Oxidation of the donors by intramolecular electron transfer from the photo-oxidized Ru(III) complex was demonstrated using optical flash photolysis and EPR experiments. A step-wise electron transfer Mn → tyrosine → Ru(III) was demonstrated, in a sequence analogous to reactions of the PSII donor side. by Oldenbourg Wissenschaftsverlag, Muenchen.