194232-63-8

Basic information

• Product Name: 2''-(tert-Butyl-diphenyl-silanyloxymethyl)-[2,4';2',4'']teroxazole-4-carbaldehyde
• Synonyms: 2''-(tert-Butyl-diphenyl-silanyloxymethyl)-[2,4';2',4'']teroxazole-4-carbaldehyde
• CAS NO: 194232-63-8
• Molecular Weight: 499.598
• Mol File: 194232-63-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2''-(tert-Butyl-diphenyl-silanyloxymethyl)-[2,4';2',4'']teroxazole-4-carbaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: 2''-(tert-Butyl-diphenyl-silanyloxymethyl)-[2,4';2',4'']teroxazole-4-carbaldehyde(194232-63-8)
• EPA Substance Registry System: 2''-(tert-Butyl-diphenyl-silanyloxymethyl)-[2,4';2',4'']teroxazole-4-carbaldehyde(194232-63-8)

Safety Data

• Hazardous Substances Data: 194232-63-8(Hazardous Substances Data)

Upstream product

• 194232-60-5 2'-(tert-Butyl-diphenyl-silanyloxymethyl)-[2,4']bioxazolyl-4-carboxylic acid amide 
• 194232-58-1 2'-((E)-Styryl)-[2,4']bioxazolyl-4-carboxylic acid ethyl ester 
• 194232-59-2 2'-Hydroxymethyl-[2,4']bioxazolyl-4-carboxylic acid ethyl ester 
• 194232-57-0 2-((E)-Styryl)-oxazole-4-carboxylic acid amide 
• 100045-76-9 2'-Hydroxymethyl-[2,4']bioxazolyl-4-carboxylic acid amide 
• 132629-37-9 ethyl 2-[(E)-2-phenylethenyl]oxazole-4-carboxylate 
• 194232-62-7 2''-(tert-Butyl-diphenyl-silanyloxymethyl)-[2,4';2',4'']teroxazole-4-carboxylic acid ethyl ester 

Downstream Products

• 213738-57-9 2''-(tert-Butyl-diphenyl-silanyloxymethyl)-4-((1R,2R)-2-[1,3]dithian-2-yl-1-methoxy-propyl)-[2,4';2',4'']teroxazole 
• 213738-71-7 (2R,3R)-3-[2''-(tert-Butyl-diphenyl-silanyloxymethyl)-[2,4';2',4'']teroxazol-4-yl]-3-methoxy-2-methyl-propionaldehyde 
• 262279-38-9 C₆₃H₈₂N₄O₁₄Si 
• 313696-79-6 (3S,8S,9S)-(E)-1,3-di-tert-butylsilenyldioxy-7-hydroxy-8-methyl-9-methoxy-9-(tert-butyldiphenylsiloxymethyl-2,4'-trisoxazole-4'-yl)-non-5-ene 
• 313696-94-5 (2R,3S)-3-[2''-(tert-Butyl-diphenyl-silanyloxymethyl)-[2,4';2',4'']teroxazol-4-yl]-3-methoxy-2-methyl-propionyl chloride 
• 262279-36-7 C₇₂H₁₀₅N₃O₁₆Si₂ 
• 262279-42-5 9-{2''-[14-acetoxy-16-(5,5-dimethyl-[1,3]dioxan-2-yl)-6-hydroxy-4,8-dimethoxy-5,9,13,15-tetramethyl-12-oxo-hexadec-1-enyl]-[2,4';2',4'']teroxazol-4-yl}-3-(tert-butyl-diphenyl-silanyloxy)-9-methoxy-8-methyl-7-oxo-non-5-enoic acid 
• 262279-37-8 C₆₆H₈₉N₃O₁₅Si 
• 262279-33-4 (3S,8R,9S)-(E)-tert-butyl 3-(tert-butyldiphenylsiloxy)-7-oxo-8-methyl-9-methoxy-9-(tert-butyldiphenylsiloxymethyl-2,4'-trisoxazole-4'-yl)-non-5-enoate 
• 262279-32-3 (3S,8S,9S)-(E)-tert-butyl 3-(tert-butyldiphenylsiloxy)-7-hydroxy-8-methyl-9-methoxy-9-(tert-butyldiphenylsiloxymethyl-2,4'-trisoxazole-4'-yl)-non-5-enoate 

Relevant articles and documents

Synthesis of the fully functionalized tris-oxazole fragment pound in metabolites derived from marine organisms

The synthesis of the fully functionalized tris-oxazole fragment 9 found in marine metabolites kabiramide C and halichondramide is reported employing modified Hantzsch methodology. Starting with the condensation reaction between cinnamamide 1 and ethyl bromopyruvate 2, the synthetic sequence leading to 9 was carried out in 13 steps with an overall yield of 26%.