194494-53-6Relevant articles and documents
Mechanism of the benzophenone-sensitized photolysis of O-benzoyl-N-(1- naphthoyl)-N-phenylhydroxylamine in cationic micellar media
Kaneko, Tsuyoshi,Tokue, Tatsuya,Kubo, Kanji,Sakurai, Tadamitsu
, p. 2771 - 2780 (1999)
The benzophenone-sensitized photolysis of the title hydroxylamine (1) in hexadecyltrimethylammonium chloride (HTAC) micelles was found to give benzoyloxy(2,3)- and phenyl(4,5)-migrated products, along with fragmentation products, 1-naphthanilide (6) and b
Novel photorearrangement of N-(1-Naphthoyl)-N-phenyl-O-benzoylhydroxylamine in micellar media
Kaneko, Tsuyoshi,Kubo, Kanji,Sakurai, Tadamitsu
, p. 4779 - 4782 (2007/10/03)
Analysis of the effects of added benzyl alcohol and a heavy atom (Br-) on the quantum yields for the benzophenone-sensitized reaction of the title hydroxylamine in hexadecyltrimethylammonium chloride micelles revealed that the benzoyloxy-migrated products are derived from the amidyl-benzoyloxyl radical pair that is present at the I micellar surface, whereas the amidyl-phenyl radical pair that is penetrated more deeply into the micellar interior is responsible for the appearance of the phenyl-rearranged products.