19480-04-7Relevant articles and documents
Formation of acetals under rhodium-catalyzed hydroformylation conditions in alcohols
Diebolt, Olivier,Cruzeuil, Clement,Mueller, Christian,Vogt, Dieter
supporting information; experimental part, p. 670 - 677 (2012/04/23)
Hydroformylation of terminal alkenes in alcohol solvents leads to the selective formation of the corresponding acetals. The Xantphos ligand gave the best results as well as acetal selectivities higher than 99% and linear/branched ratios of up to 52 were obtained. The scope of the reaction was studied. Acetals were found to be unreactive under hydroaminomethylation conditions. Copyright
Reactions of Ozone with 1-Methylcyclohexene and Methylenecyclohexane in Air
Hatakeyama, Shiro,Akimoto, Hajime
, p. 2701 - 2703 (2007/10/02)
Reactions of ozone with 1-methylcyclohexene and methylenecyclohexane were studied for the purpose of obtaining the reaction mechanism as a prototype of the reaction of ozone with pinenes.The similarity of the yields of corresponding gaseous products between 1-methylcyclohexene and α-pinene and between methylenecyclohexane and β-pinene indicates the similarity of the reaction mechanisms.