195298-97-6

Basic information

• Product Name: Benzene, 1,4-dimethoxy-2,3-bis[(1-methylethoxy)methyl]-
• CAS NO: 195298-97-6
• Molecular Formula: C16H26O4
• Molecular Weight: 282.38
• Mol File: 195298-97-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzene, 1,4-dimethoxy-2,3-bis[(1-methylethoxy)methyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,4-dimethoxy-2,3-bis[(1-methylethoxy)methyl]-(195298-97-6)
• EPA Substance Registry System: Benzene, 1,4-dimethoxy-2,3-bis[(1-methylethoxy)methyl]-(195298-97-6)

Safety Data

• Hazardous Substances Data: 195298-97-6(Hazardous Substances Data)

Upstream product

• 19164-83-1 1,4-dimethoxy-2,3-bis(bromomethyl)benzene 
• 67-63-0 isopropyl alcohol 

Downstream Products

• 195299-08-2 2-Azidomethyl-3-isopropoxymethyl-1,4-dimethoxy-benzene 
• 195299-07-1 2-Bromomethyl-3-isopropoxymethyl-1,4-dimethoxy-benzene 
• 195299-06-0 (2-Isopropoxymethyl-3,6-dimethoxy-phenyl)-methanol 
• 156971-87-8 2-Iodomethyl-3,6-dimethoxy-benzaldehyde 
• 195299-01-5 2-Isopropoxymethyl-3,6-dimethoxy-benzaldehyde 

Relevant articles and documents

Synthetic Study of Selective Benzylic Oxidation

Oxidation of bisbenzyl ethers was studied using 2,3-dichloro-5,6-dicyanobenzoquinone (DDQ). Compared to other benzylic oxidations such as Kornblum type reaction of benzyl bromides or MnO2 oxidation of benzyl alcohols, DDQ oxidation offered advantages of being mild and highly selective to provide monoaldehyde products. We have explored factors which influence the course of the reaction and exemplified the synthetic value of the approach by preparing a number of aromatic intermediates (7-8, 15-25).