19550-89-1

Basic information

• Product Name: 2,2-DIMETHYL-5-HEXEN-3-OL
• Synonyms: 2,2-DIMETHYL-5-HEXEN-3-OL
• CAS NO: 19550-89-1
• Molecular Formula: C₈H₁₆O
• Molecular Weight: 128.21
• Mol File: 19550-89-1.mol
• Article Data: 54

Chemical Properties

• Boiling Point: 166.5°Cat760mmHg
• Flash Point: 61.2°C
• Appearance: /
• Density: 0.834g/cm³
• Vapor Pressure: 0.592mmHg at 25°C
• Refractive Index: 1.437
• CAS DataBase Reference: 2,2-DIMETHYL-5-HEXEN-3-OL(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2-DIMETHYL-5-HEXEN-3-OL(19550-89-1)
• EPA Substance Registry System: 2,2-DIMETHYL-5-HEXEN-3-OL(19550-89-1)

Safety Data

• Hazardous Substances Data: 19550-89-1(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Tetrahedron Letters, 23, p. 3497, 1982 DOI: 10.1016/S0040-4039(00)87651-0

InChI:InChI=1/C8H16O/c1-5-6-7(9)8(2,3)4/h5,7,9H,1,6H2,2-4H3

Upstream product

• 75-84-3 2,2-dimethyl-propanol-1 
• 1730-25-2 allylmagnesium bromide 
• 688-61-9 Triallylborane 
• 630-19-3 pivalaldehyde 
• 53317-08-1 9-allyl-9-bora-bicyclo[3.3.1]nonane 
• 556-56-9 allyl iodid 
• 7393-43-3 tetraallyl tin 
• 106-95-6 allyl bromide 
• 762-72-1 allyl-trimethyl-silane 
• 627-15-6 1,3-dibromopropene 
• 24850-33-7 allyltributylstanane 
• 79-22-1 methyl chloroformate 
• 2622-05-1 allylmagnesium bromide 
• 3066-75-9 allyl diethyl phosphate 

Downstream Products

• 122293-90-7 (R)-2,2-dimethyl-5-hexen-3-yl (R)-(+)-α-methoxy-α-(trifluoromethyl)phenylacetate 
• 596851-25-1 (R)-3,3,3-Trifluoro-2-methoxy-2-phenyl-propionic acid (S)-1-tert-butyl-but-3-enyl ester 
• 188580-98-5 2,2-dimethylhex-5-en-3-yl tosylcarbamate 
• 590400-93-4 6-(2-bromo-phenyl)-2,2-dimethyl-hexan-3-one 
• 915225-54-6 5,5-dimethyl-4-[diphenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silyloxy]-1-hexene 
• 138212-44-9 trans-N-p-toluenesulfonyl-5-t-butyl-4-vinyl-2-oxazolidinone 
• 590400-96-7 benzyl-[4-(2-bromo-phenyl)-1-tert-butyl-butyl]-amine 
• 141398-79-0 4,4-Dimethyl-1,1-bis(phenylseleno)-3-pentanol 
• 141398-97-2 2,7,7-Trimethyl-4-phenylseleno-6-trimethylsilyloxy-3-octanol 
• 141398-82-5 4,4-Dimethyl-1,1-bis(phenylseleno)-3-trimethylsilyloxypentane 
• 141398-84-7 3-(tert-Butyldimethylsilyloxy)-4,4-dimethyl-1,1-bis(phenylseleno)pentane 
• 141398-94-9 (3S^*,5S^*)-2,6,6-Trimethyl-3-phenylseleno-5-trimethylsilyloxy-2-heptanol 
• 141398-94-9 (3S^*,5R^*)-2,6,6-Trimethyl-3-phenylseleno-5-trimethylsilyloxy-2-heptanol 
• 1185060-40-5 (+/-)-2,2-dimethylhex-5-en-3-yl 4-nitrophenylsulfonylcarbamate 

Relevant articles and documents

Allylation of Aldehydes with Allyltin Compounds in Acidic Aqueous Media-A Catalytic Version

Allylation reaction of aldehydes with allyltributyltin was achieved using Sn catalysts in acidic aqueous media. Exclusive aldehyde selectivity was observed for competitive reactions of aldehydes and ketones with allyltributyltin in the presence of 5 mol%

Gold(I)-Catalyzed Intramolecular Dehydrative Amination of Sulfamate Esters Tethered to Allylic Alcohols: A Strategy for the Synthesis of Cyclic Sulfamidates

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Stereoselective Barbier-Type Allylations and Propargylations Mediated by CpTiCl3

CpTiCl2, prepared in situ by manganese reduction of CpTiCl3, is an excellent new system for the Barbier-type allylation and propargylation of carbonyl compounds. It can be used in catalytic amounts when combined with Et3N·HBr/TMSBr, which acts as a regenerating system. The high regio- and stereoselectivity shown by this system makes it useful for prenylation and crotylation processes in the synthesis of natural products.

Syntheses of 4-Acetoxy-or acetylthio-2-substituted tetrahydrothiophene

The generality of a three-step route for the preparation of 4-Acetoxy-2-Alkyltetrahydrothiophenes was investigated, which started from 1-Alken-4-ols including epoxidation, mesylation and intramolecular nucleophilic substitution. 4-Acetoxy-2-Alkyltetrahydr