195516-43-9Relevant articles and documents
Novel reactivity of tetracoordinate 1,2λ4-oxaselenetanes: Oxirane formation reaction with retention of configuration
Ohno, Fumihiko,Kawashima, Takayuki,Okazaki, Renji
, p. 1671 - 1672 (2007/10/03)
Stable tetracoordinate 3-phenyl-1,2λ4-oxaselenetanes give the corresponding oxiranes upon thermolysis; in sharp contrast to Corey-Chaykovsky type reactions, oxirane formation proceeds with retention of configuration, and the reaction can be recognised as a new type of carbon-oxygen ligand coupling reaction of λ4-selenanes.