1963-36-6

Basic information

• Product Name: 4-METHOXYCINNAMALDEHYDE
• Synonyms: FEMA 3567;4-METHOXYCINNAMALDEHYDE;3-(4-METHOXYPHENYL)ACRYLALDEHYDE;(2E)-3-(4-Methoxyphenyl)-2-propenal;2-Propenal, 3-(4-methoxyphenyl)-;3-(4-methoxyphenyl)-2-propena;4-Methoxycinnamic aldehyde;Cinnamaldehyde, p-methoxy-
• CAS NO: 1963-36-6
• Molecular Formula: C₁₀H₁₀O₂
• Molecular Weight: 162.19
• EINECS: 217-807-0
• Product Categories: Aromatic Aldehydes & Derivatives (substituted)
• Mol File: 1963-36-6.mol
• Article Data: 172

Chemical Properties

• Melting Point: 55-60 °C(lit.)
• Boiling Point: 145 °C7 mm Hg(lit.)
• Flash Point: 110°C
• Appearance: /
• Density: 1.068 g/cm³
• Vapor Pressure: 0.00067mmHg at 25°C
• Refractive Index: 1.559
• Storage Temp.: Inert atmosphere,Room Temperature
• CAS DataBase Reference: 4-METHOXYCINNAMALDEHYDE(CAS DataBase Reference)
• NIST Chemistry Reference: 4-METHOXYCINNAMALDEHYDE(1963-36-6)
• EPA Substance Registry System: 4-METHOXYCINNAMALDEHYDE(1963-36-6)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36
• WGK Germany: 3
• Hazardous Substances Data: 1963-36-6(Hazardous Substances Data)

Usage

Description

4-Methoxycinnamaldehyde, also known as p-Methoxycinnamaldehyde, is an aromatic aldehyde with a spicy, floral odor. It is characterized by its cherry flesh, sweet taste with a cinnamic dry and slightly aromatic profile at concentrations between 3 to 20 ppm. 4-Methoxycinnamaldehyde has been reported to be found in baked potato, basil, and tarragon.

Uses

Used in Flavor and Fragrance Industry:
4-Methoxycinnamaldehyde is used as a flavoring agent for its cherry flesh, sweet taste, and cinnamic dry aromatic profile. It is particularly suitable for the creation of flavors in the food and beverage industry, enhancing the taste of various products.
4-Methoxycinnamaldehyde is also used as a fragrance ingredient in the perfumery industry, contributing to the spicy, floral scent of various perfumes and colognes.
Used in Chemical Research:
Due to its unique chemical properties, 4-Methoxycinnamaldehyde serves as a valuable compound in chemical research and development. It can be utilized in the synthesis of various organic compounds and may have potential applications in the pharmaceutical industry.

InChI:InChI=1/C10H10O2/c1-12-10-6-4-9(5-7-10)3-2-8-11/h2-8H,1H3/b3-2+

Upstream product

• 123-11-5 4-methoxy-benzaldehyde 
• 75-07-0 acetaldehyde 
• 53484-50-7 p-methoxycinnamyl alcohol 
• 2278-78-6 1,1,3-Triaethoxy-3-(p-methoxyphenyl)-propan 
• 132739-69-6 C-(4-Methoxy-1-vinyl)-N-phenyl nitron 
• 135386-71-9 2-Phenyl-3-(4-methoxyphenyl)-5-hydroxyisoxazolidine 
• 495-48-7 azoxybenzene 
• 37815-96-6 2-(4-methoxy-phenyl)-5-phenyl-3,6-dihydro-2H-pyran 
• 140-67-0 Estragole 
• 84-58-2 2,3-dicyano-5,6-dichloro-p-benzoquinone 
• 104-46-1 anethole 
• 7446-08-4 selenium(IV) oxide 
• 4180-23-8 E-1-(4'-methoxyphenyl)prop-1-ene 
• 64-19-7 acetic acid 

Downstream Products

• 6342-88-7 (4-methoxy-cinnamylidene)-malonic acid 
• 50667-94-2 (2E,4E)-5-(4-methoxyphenyl)penta-2,4-dienoic acid 
• 136036-51-6 (E)-9-(3-(4-methoxyphenyl)allylidene)-9H-fluorene 
• 15542-37-7 (E,E)-5-(4-methoxyphenyl)-2,4-pentadienoic acid 
• 2472-57-3 4-methoxy-cinnamaldehyde-semicarbazone 
• 1911-22-4 bis-(4-methoxy-cinnamylidene)-hydrazine 
• 830-09-1 3-(4'-methoxyphenyl)propenoic acid 
• 62643-86-1 1-(4-chlorophenyl)-5-(4-methoxyphenyl)penta-2,4-dien-1-one 
• 55284-14-5 (E)-4-chloro-N-((E)-3-(4-methoxyphenyl)allylidene)aniline 
• 27394-81-6 5-(4'-methoxyphenyl)-2,4-pentadienal 
• 4842-77-7 5-(4-methoxy-phenyl)-1-phenyl-penta-2,4-dien-1-one 
• 62378-72-7 6-(4-methoxyphenyl)-3,5-hexadiene-2-one 
• 126772-76-7 7-(4-methoxy-phenyl)-1-phenyl-hepta-1,4,6-trien-3-one 
• 25163-70-6 1,5-bis(4-methoxyphenyl)penta-2,4-dien-1-one 

Relevant articles and documents

Sodium bismuthate-induced oxidation of baccatin

Sodium bismuthate in acetic acid has proven very effective in the oxidation of allyic alcohols. An extension of this oxidation method using baccatin as the substrate has provided keto-baccatin, an important compound for the semisynthesis of Taxol and Taxotere. Copyright Taylor & Francis, Inc.

(±)-Camphor sulfonic acid assisted IBX based oxidation of 1° and 2° alcohols

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Method for preparing olefine aldehyde through catalytic oxidation of enol ether

The invention relates to the technical field of olefine aldehyde preparation, and provides a method for preparing olefine aldehyde through catalytic oxidation of enol ether. According to the invention, a palladium catalyst, a copper salt, a solvent and enol ether are mixed and subjected to a catalytic oxidation reaction to obtain olefine aldehyde. According to the method, the copper salt is used as the oxidizing agent, the mixed solvent of water and acetonitrile is used as the reaction solvent, and the volume ratio of water to acetonitrile in the mixed solvent is controlled to be (3-7): (3-7), so that the catalytic oxidation reaction can be smoothly carried out in the mixed solvent with a specific ratio, and the generation of palladium black precipitate can be avoided. The method provided by the invention has the advantages of simple steps, low reagent cost, no need of dangerous reagents, wide substrate adaptability and small catalyst dosage. Furthermore, octadecane mercaptan is added to promote the catalytic oxidation reaction, and when the dosage of the palladium catalyst is extremely low, the olefine aldehyde yield can be greatly increased by adding octadecane mercaptan.

One-Pot Preparation of (E)-α,β-Unsaturated Aldehydes by a Julia-Kocienski Reaction of 2,2-Dimethoxyethyl PT Sulfone Followed by Acid Hydrolysis

(E)-α,β-Unsaturated aldehydes were synthesized by the Julia-Kocienski reaction of 2,2-dimethoxyethyl 1-phenyl-1H-tetrazol-5-yl (PT) sulfone 3 with various aldehydes, followed by acid hydrolysis. The reaction could be carried out in one pot, and various (E)-α,β-unsaturated aldehydes were obtained in a short time and with high yields.