196392-17-3

Basic information

• Product Name: (1α,3β,5α)-3-Methyl-3-(phenylsulfonyl)-6-thiabicyclo[3.1.0]hexane
• Synonyms: (1α,3β,5α)-3-Methyl-3-(phenylsulfonyl)-6-thiabicyclo[3.1.0]hexane
• CAS NO: 196392-17-3
• Molecular Weight: 254.374
• Mol File: 196392-17-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (1α,3β,5α)-3-Methyl-3-(phenylsulfonyl)-6-thiabicyclo[3.1.0]hexane(CAS DataBase Reference)
• NIST Chemistry Reference: (1α,3β,5α)-3-Methyl-3-(phenylsulfonyl)-6-thiabicyclo[3.1.0]hexane(196392-17-3)
• EPA Substance Registry System: (1α,3β,5α)-3-Methyl-3-(phenylsulfonyl)-6-thiabicyclo[3.1.0]hexane(196392-17-3)

Safety Data

• Hazardous Substances Data: 196392-17-3(Hazardous Substances Data)

Upstream product

• 119472-51-4 [(1-Methylcyclopent-3-en-1-yl)sulfonyl]benzene 
• 599-70-2 ethyl phenyl sulfone 
• 260443-51-4 (1α,3α,5α)-3-Methyl-3-(phenylsulfonyl)-6-oxabicyclo[3.1.0]hexane 

Relevant articles and documents

The Enantioselective Conversion of Three-Membered Ring Sulfoxides (Episulfoxides) into Alkenyl Sulfoxides using Chiral Lithium Amide Bases

A novel type of chiral lithium amide base reaction, involving the rearrangement of certain types of symmetrical ring-fused episulfoxides, gives alkenyl sulfoxide products in up to 88% ee. The structure of one product, including its absolute stereochemistry, was determined by X-ray crystallography, following oxidation of the sulfoxide to the corresponding alkenyl sulfone.