196600-22-3

Basic information

• Product Name: (S)-2-((R)-12-Benzoyloxy-tridecyl)-pyrrolidine-1-carboxylic acid tert-butyl ester
• Synonyms: (S)-2-((R)-12-Benzoyloxy-tridecyl)-pyrrolidine-1-carboxylic acid tert-butyl ester
• CAS NO: 196600-22-3
• Molecular Weight: 473.696
• Mol File: 196600-22-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (S)-2-((R)-12-Benzoyloxy-tridecyl)-pyrrolidine-1-carboxylic acid tert-butyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-2-((R)-12-Benzoyloxy-tridecyl)-pyrrolidine-1-carboxylic acid tert-butyl ester(196600-22-3)
• EPA Substance Registry System: (S)-2-((R)-12-Benzoyloxy-tridecyl)-pyrrolidine-1-carboxylic acid tert-butyl ester(196600-22-3)

Safety Data

• Hazardous Substances Data: 196600-22-3(Hazardous Substances Data)

Upstream product

• 196600-10-9 (S)-Undeca-4,10-diyn-2-ol 
• 73365-02-3 tert-butoxycarbonyl-D-prolinal 
• 59378-81-3 1-(tert-butoxycarbonyl)prolin-2R-ol 
• 24424-99-5 di-tert-butyl dicarbonate 
• 871-84-1 1,7-Octadiyne 
• 68832-13-3 D-prolinol 
• 65-85-0 benzoic acid 
• 196600-11-0 (S)-2-((S)-12-Hydroxy-tridecyl)-pyrrolidine-1-carboxylic acid tert-butyl ester 

Downstream Products

• 196600-30-3 1-[(S)-2-((S)-12-Azido-tridecyl)-pyrrolidin-1-yl]-2-benzyloxy-ethanone 

Relevant articles and documents

Synthesis and absolute configuration of two defensive alkaloids from the Mexican bean beetle, Epilachna varivestis

Syntheses of (2S,12'R)-2-(12'-aminotridecyl)-pyrrolidine (1) and (28,12'R)-1-(2'-hydroxyethyl)-2-(12'-aminotridecyl)-pyrrolidine (2), two defensive alkaloids recently isolated from the Mexican bean beetle, Epilachna varivestis, are described. By a comparison of 1H NMR data of MTPA derivatives of natural alkaloid 2 with those of the synthetic standard, we confirm the (2S,12'R) configuration previously suggested for this alkaloid. Further support of these assignments was provided by the synthesis and 1H NMR investigation of(2S,12'S)-1, (2S,12'S)-2, and their MTPA derivatives.