196959-79-2Relevant articles and documents
Palladium-catalyzed phosphaketene decarbonylation: Diphosphaureylene intermediates in diphosphene formation
David, Marie-Anne,Wicht, Denyce K.,Glueck, David S.,Yap, Glenn P. A.,Liable-Sands, Louise M.,Rheingold, Arnold L.
, p. 4768 - 4770 (2008/10/08)
Pd(PPh3)4-catalyzed decarbonylation of the phosphaketene Mes* PCO (1, Mes* = 2,4,6-(t-Bu)3C6H2) gives the diphosphene Mes* P=PMes* (2). Related reactions of 1 with zerovalent Pd and Pt phosphine compl