197232-47-6

Basic information

• Product Name: (4S,5R)-1-((2R,3S)-1-Benzoyl-3-methyl-aziridine-2-carbonyl)-3,4-dimethyl-5-phenyl-imidazolidin-2-one
• CAS NO: 197232-47-6
• Molecular Weight: 377.443
• Mol File: 197232-47-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (4S,5R)-1-((2R,3S)-1-Benzoyl-3-methyl-aziridine-2-carbonyl)-3,4-dimethyl-5-phenyl-imidazolidin-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (4S,5R)-1-((2R,3S)-1-Benzoyl-3-methyl-aziridine-2-carbonyl)-3,4-dimethyl-5-phenyl-imidazolidin-2-one(197232-47-6)
• EPA Substance Registry System: (4S,5R)-1-((2R,3S)-1-Benzoyl-3-methyl-aziridine-2-carbonyl)-3,4-dimethyl-5-phenyl-imidazolidin-2-one(197232-47-6)

Safety Data

• Hazardous Substances Data: 197232-47-6(Hazardous Substances Data)

Upstream product

• 98-88-4 benzoyl chloride 
• 176791-95-0 (4R,5S)-1,5-Dimethyl-3-((2R,3S)-3-methyl-aziridine-2-carbonyl)-4-phenyl-imidazolidin-2-one 

Downstream Products

• 197232-54-5 (4R,5S)-1,5-Dimethyl-3-((4R,5S)-5-methyl-2-phenyl-4,5-dihydro-oxazole-4-carbonyl)-4-phenyl-imidazolidin-2-one 

Relevant articles and documents

Ring expansion of N-acetyl aziridine-2-imides to oxazoline-4-imides, useful precursors of pure β-hydroxy α-aminoacids

Optically active N-acyl aziridine 2-imides or α-carboxylates rearrange to oxazoline-4-imides or 4-carboxylates with high regio and stereo control. This ring expansion followed by mild hydrolisis allows the synthesis of enantiomerically pure β-hydroxy α-aminoacid precursors.