19780-10-0Relevant articles and documents
SELENOESTERS IN ORGANIC SYNTHESIS. 2. NEW SYNTHESIS OF SATURATED AND α,β-UNSATURATED KETONES AND THE SYNTHESIS OF THE PEACH MOTH PHEROMONE (Carposia niponensis)
Sviridov, A. F.,Ermolenko, M. S.,Yashunskii, D. V.,Kochetkov, N. K.
, p. 1514 - 1518 (1985)
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A simple synthesis of ketone from carboxylic acid using tosyl chloride as an activator
Jana, Samaresh,Sahoo, Debasis,Sarkar, Sohini
supporting information, (2019/09/06)
An effective process for the conversion of carboxylic acid to ketone has been discovered. In this process, carboxylic acid has been activated using p-toluene sulphonyl group. Under the optimized condition, aromatic, aliphatic heteroaromatic carboxylic acids have been proved to be good substrates for this methodology. The byproduct of this reaction can be removed very easily during work up process. Also, one equivalent of organometallic reagent is sufficient to complete this transformation.
Simple one pot synthesis of ketone from carboxylic acid using DCC as an activator
Mekonnen, Habtamu Gelaw,Jana, Samaresh
supporting information, p. 1382 - 1384 (2019/04/30)
Simple one pot procedure for the conversion of carboxylic acid to ketone is described. Various carboxylic acids were converted to the corresponding ketones in excellent manner in presence of N,N′-dicyclohexylcarbodiimide (DCC) and organometallic reagents. Aromatic, heteroaromatic and aliphatic acids were converted to the corresponding ketones smoothly under the optimum conditions using organolithium reagents. In this process, desired products have been isolated from the crude reaction mixtures in moderate yields during the purification process.
Nickel-catalyzed cross-coupling of non-activated and functionalized alkyl halides with alkyl grignard reagents
Vechorkin, Oleg,Hu, Xile
supporting information; experimental part, p. 2937 - 2940 (2009/09/08)
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