197916-07-7

Basic information

• Product Name: 2-allyloxy-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran
• Synonyms: 2-allyloxy-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran
• CAS NO: 197916-07-7
• Molecular Weight: 474.597
• Mol File: 197916-07-7.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 2-allyloxy-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran(CAS DataBase Reference)
• NIST Chemistry Reference: 2-allyloxy-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran(197916-07-7)
• EPA Substance Registry System: 2-allyloxy-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran(197916-07-7)

Safety Data

• Hazardous Substances Data: 197916-07-7(Hazardous Substances Data)

Upstream product

• 6014-42-2 L-rhamnose 
• 73-34-7 L-rhamnose 
• 64650-81-3 allyl α-L-rhamnopyranoside 
• 100-39-0 benzyl bromide 

Downstream Products

• 86795-39-3 (2S,3R,4R,5S,6S)-3,4,5-tris(benzyloxy)-2-chloro-6-methyltetrahydro-2H-pyran 
• 210426-02-1 2,3,4-tri-O-benzyl-L-rhamnopyranose 
• 157889-69-5 C₂₀H₂₄O₅ 
• 1310869-80-7 C₂₃H₂₈O₅ 
• 157889-68-4 2,4-di-O-benzyl-α-L-rhamnopyranoside 
• 124943-18-6 allyl 2,4-di-O-benzyl-α-L-rhamnopyranoside 
• 1310869-83-0 C₂₂H₂₆O₆ 
• 1275596-88-7 3-(((2R,3R,4R,5S,6S)-3,4,5-tris(benzyloxy)-6-methyltetrahydro-2H-pyran-2-yl)oxy)propan-1-ol 

Relevant articles and documents

Highly regioselective and stereoselective synthesis of C-Aryl glycosidesvianickel-catalyzedortho-C-H glycosylation of 8-aminoquinoline benzamides

C-Aryl glycosides are of high value as drug candidates. Here a novel and cost-effective nickel catalyzedortho-CAr-H glycosylation reaction with high regioselectivity and excellent α-selectivity is described. This method shows great functional group compatibility with various glycosides, showing its synthetic potential. Mechanistic studies indicate that C-H activation could be the rate-determining step.

Facile glycosylation strategy with two-stage activation of allyl glycosyl donors. Application to concise synthesis of Shigella flexneri serotype y O-antigen

A practical, useful glycosylation method employing only allyl glycoside building blocks has been developed. The donor's glycosylation reactivity is turned on via isomerization of its anomeric allyl protecting group into the corresponding prop-1-enyl moiet