19850-36-3

Basic information

• Product Name: 6-({[2-(methylsulfanyl)phenyl]amino}methylidene)cyclohexa-2,4-dien-1-one
• CAS NO: 19850-36-3
• Molecular Formula: C₁₄H₁₃NOS
• Molecular Weight: 243.3241
• Mol File: 19850-36-3.mol
• Article Data: 8

Chemical Properties

• Boiling Point: 394.1°C at 760 mmHg
• Flash Point: 192.2°C
• Density: 1.21g/cm³
• Vapor Pressure: 2.03E-06mmHg at 25°C
• Refractive Index: 1.647
• CAS DataBase Reference: 6-({[2-(methylsulfanyl)phenyl]amino}methylidene)cyclohexa-2,4-dien-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 6-({[2-(methylsulfanyl)phenyl]amino}methylidene)cyclohexa-2,4-dien-1-one(19850-36-3)
• EPA Substance Registry System: 6-({[2-(methylsulfanyl)phenyl]amino}methylidene)cyclohexa-2,4-dien-1-one(19850-36-3)

Safety Data

• Hazardous Substances Data: 19850-36-3(Hazardous Substances Data)

Upstream product

• 2987-53-3 2-(Methylthio)aniline 
• 90-02-8 salicylaldehyde 

Downstream Products

• 1426330-56-4 C₃₄H₃₈N₂O₄S₂Ti 

Relevant articles and documents

ONS-donor ligand based Pt(II) complexes display extremely high anticancer potency through autophagic cell death pathway

The current study unveils ONS-donor ligand based Pt(II) complexes with unusual anticancer potency showing higher anticancer effect as compared to cisplatin. This series of Pt(II)(R-salicylaldimine)Cl (C1a-C4a) (R = 5-H, 5-CH3, F, 3-CH3/su

Ruthenium complexes bearing tridentate 2-(methylthio)phenylsalicylaldimine Schiff-base ligands

Reaction of [Ru(PPh3)3Cl2] with 2-(methylthio)phenylsalicylaldimine Schiff-base (HL) in tetrahydrofuran (THF) in the presence of triethylamine afforded a ruthenium(II) complex [Ru(ONS-L)(PPh3)2Cl]·CH3OH·2.75H2O (1). Similarly, reaction of [Ru(CO)2Cl2] with HL in N,N′-dimethylformamide (DMF) in the presence of triethylamine gave a ruthenium(II) complex [Ru(ONS-L)(CO)2Cl] (2), while the reaction between [Ru(CO)2Cl2] and HL without base resulted in a ruthenium(III) complex [Ru(ONS-L)(CO)Cl2] (3). Treatment of RuCl3·3H2O with HL in ethanol in the presence of triethylamine gave an anionic complex [Et3NH][Ru(ONS-L)Cl3] (4), which reacted with [Cp?2Ru] in the presence of sodium hydroxide to give complex [Cp?Ru(η6-1,2,3,4-Me4C6H2)][Ru(ONS-L)Cl3]·CH2Cl2 (5) with a different cation. Besides, reaction of 4 and AgNO3 afforded a dinuclear ruthenium(II) complex [Ru2(ONS-L)(μ-ONS-L)2Cl]·CH2Cl2 (6). The structures of complexes 1–6 have been established by X-ray crystallography, of which complex 4 was selected as a catalyst for the typical oxidation of 1-phenylethanol to the according acetophenone.

The enhanced catalytic performance of cobalt catalysts towards butadiene polymerization by introducing a labile donor in a salen ligand

A family of cobalt complexes supported by a tridentate Schiff base ligand with a labile donor (O, S, N) as a pendant arm (Co1-Co12, formulated as CoL 2) were synthesized by the treatment of the corresponding ligands with cobalt acetate tetrahyd