19871-30-8

Basic information

• Product Name: S,S-dimethyl-N-(phenylsulfonyl)sulfimide
• Synonyms: S,S-dimethyl-N-(phenylsulfonyl)sulfimide
• CAS NO: 19871-30-8
• Molecular Weight: 217.313
• Mol File: 19871-30-8.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: S,S-dimethyl-N-(phenylsulfonyl)sulfimide(CAS DataBase Reference)
• NIST Chemistry Reference: S,S-dimethyl-N-(phenylsulfonyl)sulfimide(19871-30-8)
• EPA Substance Registry System: S,S-dimethyl-N-(phenylsulfonyl)sulfimide(19871-30-8)

Safety Data

• Hazardous Substances Data: 19871-30-8(Hazardous Substances Data)

Upstream product

• 75-18-3 dimethylsulfide 
• 127-52-6 chloramine-B 
• 98-10-2 benzenesulfonamide 
• 3729-56-4 N-(4-Nitro-benzolsulfonyloxy)-benzolsulfonamid 
• 1087391-80-7 benzenesulfonamide sodium salt 
• 145490-75-1 N-fluorobenzene sulfonamide 
• 80-16-0 N-chlorobenzenesulfonamide 
• 882-33-7 diphenyldisulfane 
• 599-71-3 piloty's acid 
• 67-56-1 methanol 
• 61945-92-4 N,N'-di(phenylsulfonyl)selenium diimide 
• 67-68-5 dimethyl sulfoxide 
• 72647-81-5 N-phenylsulfonyl-N'-(2,6-dimethylpyrimidin-4-yl)urea 
• 2845-62-7 benzenesulphonyl isocyanate 

Downstream Products

• 98-10-2 benzenesulfonamide 
• 75-18-3 dimethylsulfide 
• 67-68-5 dimethyl sulfoxide 
• 22236-46-0 N-(dimethyl(oxo)-λ6-sulfanylidene)benzenesulfonamide 

Relevant articles and documents

Synthesis of acyclic α- and β-silyl sulfimides

Conversion of acyclic α- and β-silyl Sulfides by their treatment with sodium salts of N-chlorosulfonamides into the corresponding previously unknown sulfimides is described. The process is accompanied by a competing reaction resulting in the formation of α- or β-silyl sulfoxides. β-Silyl sulfamide (9b) undergoes thermolysis to generate trimethylvinylsilane. The Royal Society of Chemistry 2000.

Copper-catalyzed imination of sulfoxides and sulfides

Sulfoximines and sulfilimines have attracted considerable interest among organic chemists. The Cu(II)-catalyzed imination of sulfoxides and sulfides using various N-fluoro benzenesulfonamides was investigated in this study. The scope of the reaction was demonstrated by using several substituted sulfides and sulfoxides. The flow strategy for the preparation of NH-sulfoximines was also examined. By trapping nitrene intermediates through triphenylphosphine, we found that the reaction was conducted through a metal-nitrene intermediate mechanism.

REACTIONS OF ISOCYANATES WITH SULFOXIDES

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