199615-24-2

Basic information

• Product Name: (2R,1'R)-[1'-(1-naphthyl)ethyl]-4-phenyl-2-butylamine
• Synonyms: (2R,1'R)-[1'-(1-naphthyl)ethyl]-4-phenyl-2-butylamine
• CAS NO: 199615-24-2
• Molecular Weight: 303.447
• Mol File: 199615-24-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2R,1'R)-[1'-(1-naphthyl)ethyl]-4-phenyl-2-butylamine(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,1'R)-[1'-(1-naphthyl)ethyl]-4-phenyl-2-butylamine(199615-24-2)
• EPA Substance Registry System: (2R,1'R)-[1'-(1-naphthyl)ethyl]-4-phenyl-2-butylamine(199615-24-2)

Safety Data

• Hazardous Substances Data: 199615-24-2(Hazardous Substances Data)

Upstream product

• 3886-70-2 (R)-1-(1-Naphthyl)ethylamine 
• 104-53-0 3-phenyl-propionaldehyde 
• 917-54-4 methyllithium 
• 254745-24-9 (R)-N-(3-phenylpropylidene)-1-(1-napthyl)ethylamine 

Downstream Products

• 137029-98-2 (R)-N-(p-toluenesulfonyl)-1-methyl-3-phenylpropylamine 
• 937-52-0 (R)-1-methyl-3-phenylpropylamine 

Relevant articles and documents

Asymmetric addition of alkyllithium to chiral imines: α-Naphthylethyl group as a chiral auxiliary

The diastereoselective nucleophilic addition of alkyllithium to N- alkylidene-α-naphthylethylamine was carried out. In the presence of Lewis acids or Lewis bases, organolithiums reacted smoothly with imines to give the corresponding amines in high stereoselectivity (up to 100% de). Furthermore, the resulting optically active amines were found to be useful for asymmetric reactions as chiral ligands.