200192-51-4Relevant articles and documents
Homoallyl-cyclopropylcarbinyl cation manifold. Trimethylsilyl versus aryl stabilization
Creary, Xavier,O'Donnell, Benjamin D.,Vervaeke, Marie
, p. 3360 - 3368 (2008/02/03)
(Chemical Equation Presented) A series of E- and Z-1-aryl-5-trimethylsilyl- 3-buten-1-yl trifluoroacetates were solvolyzed in CD3CO2D, and rates of reaction as well as products derived from these reactions were determined. Hammett pl
Stereoselective synthesis of 2,3,5-trisubstituted tetrahydrofurans by an allyl silane metathesis - Nucleophilic addition sequence
Cassidy, John H.,Marsden, Stephen P.,Stemp, Geoffrey
, p. 1411 - 1413 (2007/10/03)
Functionalised cyclic allyl silanes have been prepared by the ring closing metathesis of allyldimethylsilyl ethers of homoallylic alcohols. Treatment of these allyl silanes with aldehydes in the presence of boron trifluoride etherate gives high yields of