201226-87-1

Basic information

• Product Name: 2,7-Di-tert-butyl-9,9-dimethyl-4-((R)-methyl-phenyl-phosphinoyl)-5-((S)-methyl-phenyl-phosphinoyl)-9H-xanthene
• Synonyms: 2,7-Di-tert-butyl-9,9-dimethyl-4-((R)-methyl-phenyl-phosphinoyl)-5-((S)-methyl-phenyl-phosphinoyl)-9H-xanthene
• CAS NO: 201226-87-1
• Molecular Weight: 598.702
• Mol File: 201226-87-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,7-Di-tert-butyl-9,9-dimethyl-4-((R)-methyl-phenyl-phosphinoyl)-5-((S)-methyl-phenyl-phosphinoyl)-9H-xanthene(CAS DataBase Reference)
• NIST Chemistry Reference: 2,7-Di-tert-butyl-9,9-dimethyl-4-((R)-methyl-phenyl-phosphinoyl)-5-((S)-methyl-phenyl-phosphinoyl)-9H-xanthene(201226-87-1)
• EPA Substance Registry System: 2,7-Di-tert-butyl-9,9-dimethyl-4-((R)-methyl-phenyl-phosphinoyl)-5-((S)-methyl-phenyl-phosphinoyl)-9H-xanthene(201226-87-1)

Safety Data

• Hazardous Substances Data: 201226-87-1(Hazardous Substances Data)

Upstream product

• 130525-43-8 4,5-dibromo-2,7-di-tert-butyl-9,9-dimethyl-9H-xanthene 
• 15849-86-2 methyl(phenyl)chlorophosphine 

Downstream Products

• 201226-91-7 2,7-Di-tert-butyl-9,9-dimethyl-4,5-bis-((R)-methyl-phenyl-phosphinoyl)-9H-xanthene 
• 201226-88-2 2,7-Di-tert-butyl-9,9-dimethyl-4-((R)-methyl-phenyl-phosphanyl)-5-((S)-methyl-phenyl-phosphanyl)-9H-xanthene 

Relevant articles and documents

Synthesis and application of new chiral bidentate phosphine, 2,7-di-tert-butyl-9,9-dimethyl-4,5-bis (methylphenylphosphino)xanthene

New optically active bidentate phosphines, (S,S)- and (R,R)-2,7-di-tert-butyl-9,9-dimethyl-4, 5-bis(methylphenylphosphino)xanthenes ((S,S)-1 and (R,R)-1), were prepared through resolution of the corresponding phosphine oxides using (R, R)-(-)-dibenzoyl-tartaric acid and a preliminary experiment on asymmetric synthesis using an allyl substrate proved the utility of the new bidentate phosphines.