201274-51-3

Basic information

• Product Name: 1-[2-(Benzyloxy)-6,7-dihydro-5H-cyclopenta[b]pyridin-3-yl]-3-[6-(benzyloxy)pyridin-2-yl]prop-2-yn-1-ol
• Synonyms: 1-[2-(Benzyloxy)-6,7-dihydro-5H-cyclopenta[b]pyridin-3-yl]-3-[6-(benzyloxy)pyridin-2-yl]prop-2-yn-1-ol
• CAS NO: 201274-51-3
• Molecular Weight: 462.548
• Mol File: 201274-51-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-[2-(Benzyloxy)-6,7-dihydro-5H-cyclopenta[b]pyridin-3-yl]-3-[6-(benzyloxy)pyridin-2-yl]prop-2-yn-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 1-[2-(Benzyloxy)-6,7-dihydro-5H-cyclopenta[b]pyridin-3-yl]-3-[6-(benzyloxy)pyridin-2-yl]prop-2-yn-1-ol(201274-51-3)
• EPA Substance Registry System: 1-[2-(Benzyloxy)-6,7-dihydro-5H-cyclopenta[b]pyridin-3-yl]-3-[6-(benzyloxy)pyridin-2-yl]prop-2-yn-1-ol(201274-51-3)

Safety Data

• Hazardous Substances Data: 201274-51-3(Hazardous Substances Data)

Upstream product

• 360774-14-7 2-(Benzyloxy)-6,7-dihydro-5H-cyclopenta[b]pyridine-3-carbonitrile 
• 100-39-0 benzyl bromide 
• 120-92-3 cyclopentanone 
• 108106-97-4 2-oxo-2,5,6,7-tetrahydro-3-cyano-1H-cyclopenta[b]pyridine-3-carbonitrile 
• 134080-69-6 2-ethynyl-6-(phenylmethoxy)pyridine 
• 201274-49-9 2-(Benzyloxy)-6,7-dihydro-5H-cyclopenta[b]pyridine-3-carbaldehyde 

Downstream Products

• 234752-98-8 2-(Benzyloxy)-3-(3-[6-(benzyloxy)pyridin-2-yl]-1-{[tert-butyl(dimethyl)silyl]oxy}prop-2-ynyl)-6,7-dihydro-5H-cyclopenta[b]pyridine 

Relevant articles and documents

Fusicoccin ring system by [4 + 4] cycloaddition. 2. A model study

A synthetic approach to fusicoccin A utilizing intramolecular photocycloaddition of tethered 2-pyridones has been completed. This study has led to the first solvent-dependent 2-pyridone photocycloaddition yielding either cis or trans products. Epoxidation of the cis photoproduct is selective for the disubstituted alkene, stabilizes the product, and is properly located for installation of the trans-1,2-diol. Activation of the secondary amide by reaction with an isocyanate led to the reduction of the neopentyl amide carbonyl to a methyl group.