201279-57-4

Basic information

• Product Name: (S)-benzoic acid 1-furan-2-yl-ethyl ester
• Synonyms: (S)-benzoic acid 1-furan-2-yl-ethyl ester
• CAS NO: 201279-57-4
• Molecular Weight: 216.236
• Mol File: 201279-57-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (S)-benzoic acid 1-furan-2-yl-ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-benzoic acid 1-furan-2-yl-ethyl ester(201279-57-4)
• EPA Substance Registry System: (S)-benzoic acid 1-furan-2-yl-ethyl ester(201279-57-4)

Safety Data

• Hazardous Substances Data: 201279-57-4(Hazardous Substances Data)

Upstream product

• 4208-64-4 (S)-1-(2-furanyl)ethanol 
• 60718-51-6 1-benzoyl-1,2,4-triazole 
• 98-88-4 benzoyl chloride 

Relevant articles and documents

Asymmetry induction on the [4C(4π)+3C(2π)] cycloaddition reaction of C2-functionalized furans: Influence of the chiral auxiliary nature

The study of the π-facial diastereoselectivity in the [4+3] cycloaddition reaction of thirteen different chiral 2-substituted furans with oxyallyl cations, under sonochemical and/or thermal conditions, is presented. In almost all studied furans, a cis diastereoselectivity and a high endo diastereoselectivity is observed. Decreasing the distance between the closest stereocenter of the chiral auxiliary and the reactive C2-carbon of the furan ring, increases the π-facial diastereoselectivity, especially by using chiral furyl-sulfoxides.

The configurational assignment of the optically active 5-(1-hydro- peroxyethyl)-3-ethoxycarbonyl-2-methylfuran and its alcohol by exciton- coupled circular dichroism (ECCD)

The absolute configuration of the furan-derived hydroperoxide 1 and its alcohol 2, readily available in optically active form by kinetic resolution of the racemic hydroperoxide with horseradish peroxidase (HRP), was determined by the exciton-coupled circular dichroism (ECCD) method on their 2-naphthoate derivatives 4.