201300-96-1

Basic information

• Product Name: 2-Oxazolidinone, 3-(2-bromo-1-oxopropyl)-4-phenyl-, (4R)-
• CAS NO: 201300-96-1
• Molecular Formula: C12H12BrNO3
• Molecular Weight: 298.136
• Mol File: 201300-96-1.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 2-Oxazolidinone, 3-(2-bromo-1-oxopropyl)-4-phenyl-, (4R)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Oxazolidinone, 3-(2-bromo-1-oxopropyl)-4-phenyl-, (4R)-(201300-96-1)
• EPA Substance Registry System: 2-Oxazolidinone, 3-(2-bromo-1-oxopropyl)-4-phenyl-, (4R)-(201300-96-1)

Safety Data

• Hazardous Substances Data: 201300-96-1(Hazardous Substances Data)

Upstream product

• 90319-52-1 (4R)-phenyl-2-oxazolidinone 
• 56613-80-0 D-2-phenylglycinol 
• 369624-76-0 (4'R)-2-bromo-3-methyl-1-(2'-oxo-4'-phenyloxazolidin-3'-yl)butan-1-one 
• 7148-74-5 2-Bromopropionyl chloride 
• 563-76-8 α-bromopropionyl bromide 

Downstream Products

• 455913-33-4 3-(2R-methoxycarbonylpropionyl)-4R-phenyl-2-oxazolidinone 
• 455913-31-2 3-(2S-methoxycarbonylpropionyl)-4R-phenyl-2-oxazolidinone 
• 160695-26-1 (4R)-3-propionyl-4-phenyl-1,3-oxazolidin-2-one 
• 90319-52-1 (4R)-phenyl-2-oxazolidinone 
• 192864-91-8 (4S)-4-benzyl-3-(2-bromopropanoyl)-1,3-oxazolidin-2-one 
• 114418-61-0 (3S,4R)-3-<(R)-1-(t-Butyldimethylsilyloxy)ethyl>-4-<(S)-1-((R)-4-phenyl-2-oxazolidone-3-carbonyl)ethyl>-2-azetidinone 
• 114341-85-4 (3S,4R)-3-<(R)-1-(t-Butyldimethylsilyloxy)ethyl>-4-<(R)-1-((R)-4-phenyl-2-oxazolidone-3-carbonyl)ethyl>-2-azetidinone 
• 133467-37-5 (4S)-3-[(2S,3S)-3-hydroxy-2-methyl-3-phenylpropanoyl]-4-benzyl-2-oxazolidinone 

Relevant articles and documents

Stereoselective dimerization of chiral α-bromoamides promoted by Fe(Co)5

Organic α-bromocarboxylates react with aldehydes and ketones in the presence of Fe(CO)5 (the Reformatsky-type reactions). Unlike them, N-oxazolidinone derivatives of the same acids undergo diastereoselective reductive dimerization to give (2S,3S)-dimers, regardless of the configuration of the α-chiral center in the starting reagent.

Heterocyclic compounds and their production

A compound of the formula: STR1 wherein R1, R2, R3 and R4 are each a hydrogen atom, a lower alkyl group, an ar(lower)alkyl group or an aryl group, or R1 and R2 may be combined together to f

A highly stereoselective synthesis of a key intermediate of 1β-methylcarbapenems employing the Reformatsky reaction of 3-(2-bromopropionyl)-2-oxazolidone derivatives

-