201350-82-5Relevant articles and documents
Photoisomerization of 2,4,4,6-tetraaryl-4H-selenopyrans: A new heterocyclic ring contraction
Kroulík,?ejka,?ebek,Sedmera,Halada,Havlí?ek,Ne?p?rek,Kratochvíl,Kuthan
, p. 90 - 91 (2001)
The UV illumination of title compounds 3a,b in acetonitrile solutions leads to corresponding five-membered ring isomers 4a,b, probably, via open-ring intermediates, whereas the photocolouration was observed in the solid state.
Substituted 2,4,4,6-tetraphenyl-4H-selenopyrans: Preparation, photocolouration and 4H-selenopyran ring geometry; an X-ray and DFT calculation study
Kroulik, Jiri,Cejka, Jan,Boehm, Stanislav,Sebek, Pavel,Nespurek, Stanislav,Koshets, Igor,Sedmera, Petr,Halada, Petr,Havlicek, Vladimir,Kratochvil, Bohumil,Kuthan, Josef
, p. 1909 - 1916 (2007/10/03)
1,5-Diaryl-3,3-diphenylpentane-1,5-diones 3a-d react with Al2Se3-HCl-AcOH reagent to give the 2,6-diaryl-4,4-diphenyl-4H-selenopyrans 4a-d in satisfactory yields while the same procedure starting from 1,5-diketone 5 affords small amo