20152-33-4

Basic information

• Product Name: Silane, (1,1-dimethylethyl)dimethyl[(2-methyl-1-cyclohexen-1-yl)oxy]-
• CAS NO: 20152-33-4
• Molecular Formula: C13H26OSi
• Molecular Weight: 226.434
• Mol File: 20152-33-4.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: Silane, (1,1-dimethylethyl)dimethyl[(2-methyl-1-cyclohexen-1-yl)oxy]-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, (1,1-dimethylethyl)dimethyl[(2-methyl-1-cyclohexen-1-yl)oxy]-(20152-33-4)
• EPA Substance Registry System: Silane, (1,1-dimethylethyl)dimethyl[(2-methyl-1-cyclohexen-1-yl)oxy]-(20152-33-4)

Safety Data

• Hazardous Substances Data: 20152-33-4(Hazardous Substances Data)

Upstream product

• 1713-33-3 1,2-epoxy-1-methylcyclohexane 
• 56522-24-8 tert-butyldimethylsilyl cyanide 
• 20152-34-5 1-tert-butyldimethylsilyloxy-6-methyl-1-cyclohexene 
• 77086-38-5 ketene t-butyldimethylsilyl methyl acetal 
• 583-60-8 2-Methylcyclohexanone 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 591-49-1 1-methylcyclohex-1-ene 
• 82112-21-8 N,O-bis(tertbutyldimethylsilyl)acetamide 
• 69739-34-0 t-butyldimethylsiyl triflate 

Downstream Products

• 94089-47-1 3-(1-methyl-2-oxocyclohexyl)propionic acid methyl ester 
• 4071-58-3 2-methyl-2-(3'-oxobutyl)cyclohexan-1-one 
• 938-07-8 trans-10-methyldecal-2-one 
• 881417-53-4 2-Methyl-2-{2-[3-phenylsulfanyl-cyclohex-2-en-(E)-ylidene]-ethyl}-cyclohexanone 
• 827008-20-8 2-[2-(6-methoxy-3,4-dihydro-2H-naphthalen-1-ylidene)-ethyl]-2-methyl-cyclohexanone 
• 83681-07-6 N-<(p-bromophenyl)sulfonyl>-1-methylcyclopentanecarboxamide 

Relevant articles and documents

SYNTHESIS OF t-BUTYLDIMETHYLSILYL ENOL ETHERS FROM STERICALLY HINDERED KETONES

Ketones react rapidly with t-butyldimethylsilyl triflate and amine bases to form t-butyldimethylsilyl enol ethers in high yield.

Facile isomerization of silyl enol ethers catalyzed by triflic imide and its application to one-pot isomerization-(2 + 2) cycloaddition

A triflic imide (Tf2NH) catalyzed isomerization of kinetically favourable silyl enol ethers into thermodynamically stable ones was developed. We also demonstrated a one-pot catalytic reaction consisting of (2 + 2) cycloaddition and isomerization. In the reaction sequence, Tf2NH catalyzes both of the reactions.

N-heterocyclic carbene-catalyzed silyl enol ether formation

N-Heterocyclic carbenes (NHCs) were found to catalyze the silyl transfer from trialkylsilyl ketene acetals to ketones. In the presence of a catalytic amount of NHC 3 (IAd, 0.1 to 5 mol%), a series of enolizable ketones as well as cyclohexanecarboxaldehyde