201863-16-3Relevant articles and documents
Preparation, characterization, and X-ray structure of the 1:1 complex of o-acetylstyrene and carbonylbis(triphenylphosphine)ruthenium. A new catalyst for the copolymerization of acetophenone and 1,3-divinyltetramethyldisiloxane
Lu, Ping,Paulasaari, Jyri,Jin, Kevin,Bau, Robert,Weber, William P.
, p. 584 - 588 (2008/10/08)
Treatment of dihydridocarbonyltris(triphenylphosphine)ruthenium with a stoichiometric amount of styrene, followed by addition of o-acetylstyrene leads to a 1:1 complex of o-acetylstyrene and carbonylbis(triphenylphosphine)ruthenium. This species has been fully characterized and its structure determined by X-ray crystallography. This 1:1 complex is able to catalyze the copolymerization of acetophenone and 1,3-divinyltetramethyldisiloxane.