202577-46-6Relevant articles and documents
Synthesis of pyridinium dinitrobenzyl sufates and potassium (Dinitrobenzyl β-D-glucopyranosid) uronates
Mori, Masa-Aki,Dohrin, Masahiro,Sayama, Michio,Shoji, Miki,Inoue, Masami,Kozuka, Hiroshi
, p. 145 - 147 (1998)
Sulfates and glucoronides of 2,4-dinitrobenzyl alcohol 1a an 2,6- dinitrobenzyl alcohol 1b, which are major or putative metabolites of 2,4- dinitrotoluene (2,4-DNT) and 2,6-dinitrotoluene (2,6-DNT), were synthesized from 1a and 1b by reaction with pyridinium sulfonate and methyl (2,3,4-tri- O-acetyl-α-D-glucopyranosyl)uronate bromide 3, respectively, as their pyridinium salts (2a, 2b) and potassium salts (6a, 6b). These conugates are important for the study of carcinogenicity of 2,4-DNT and 2,6-DNT.