20259-40-9

Basic information

• Product Name: Diisobutyl[(E)-1-hexenyl] aluminum
• Synonyms: [(E)-1-Hexenyl]bis(2-methylpropyl)aluminum;Diisobutyl[(E)-1-hexenyl] aluminum
• CAS NO: 20259-40-9
• Molecular Formula: C₁₄H₂₉Al
• Molecular Weight: 224.3616
• Mol File: 20259-40-9.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 62.8°Cat760mmHg
• Flash Point: °C
• Appearance: /
• Density: g/cm³
• Vapor Pressure: 188mmHg at 25°C
• CAS DataBase Reference: Diisobutyl[(E)-1-hexenyl] aluminum(CAS DataBase Reference)
• NIST Chemistry Reference: Diisobutyl[(E)-1-hexenyl] aluminum(20259-40-9)
• EPA Substance Registry System: Diisobutyl[(E)-1-hexenyl] aluminum(20259-40-9)

Safety Data

• Hazardous Substances Data: 20259-40-9(Hazardous Substances Data)

Usage

InChI:InChI=1/C6H11.2C4H9.Al/c1-3-5-6-4-2;2*1-4(2)3;/h1,3H,4-6H2,2H3;2*4H,1H2,2-3H3;/q3*-1;+3

Upstream product

• 14343-59-0 1,1-bis(diisobutylaluminium)hexane 

Downstream Products

• 71964-05-1 (E)-1-(hex-1-en-1-ylsulfonyl)-4-methylbenzene 
• 98-59-9 p-toluenesulfonyl chloride 

Relevant articles and documents

Aluminium-Carbon Bond Reactivity in Geminal Organodialuminium Compounds

The reactions of 1,1-bis(diisobutylaluminium)hexane (1) with diethylamine, N-methylaniline, methanol and m-cresol have been studied.During partial protolysis both the aluminium-i-butyl bond and the aluminium-carbon bond in the aluminium-carbon-aluminium bridge undergo cleavage.The route of protolysis mainly depends on the protolytic agent used.The reaction of (1) with acetone has also been studied.Acetone was reduced to i-butanol with a 95percent yield.The ratio of the i-butyl to hexylidene groups from β-hydride elimination is 2:1.