20259-78-3

Basic information

• Product Name: 5-(4-aminophenyl)silatrane
• Synonyms: 5-(4-aminophenyl)silatrane
• CAS NO: 20259-78-3
• Molecular Weight: 266.372
• Mol File: 20259-78-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 5-(4-aminophenyl)silatrane(CAS DataBase Reference)
• NIST Chemistry Reference: 5-(4-aminophenyl)silatrane(20259-78-3)
• EPA Substance Registry System: 5-(4-aminophenyl)silatrane(20259-78-3)

Safety Data

• Hazardous Substances Data: 20259-78-3(Hazardous Substances Data)

Upstream product

• 102-71-6 triethanolamine 
• 33976-43-1 para-aminophenyltrimethoxysilane 

Relevant articles and documents

Synthesis of Silatrane-Containing Organic Sensitizers as Precursors for the Silyloxyl Anchoring Group in Dye-Sensitized Solar Cells

A series of organic D-π-A dyes, endowed with different silicon-based anchoring groups, has been prepared to assess the stability of such anchoring moieties on nanocrystalline TiO 2 in dye-sensitized solar cells. Due to the difficulties encountered in finding a reliable and robust preparation protocol to obtain pure trialkoxysilanes, replacement with a silatrane moiety was evaluated. It was found that the silatrane group could be easily introduced on three different molecular scaffolds by using a simple amide coupling reaction mediated by EDC-Cl. Furthermore, the spectroscopic properties and anchoring mode on nanocrystalline TiO 2 of the silatrane dyes were found to be nearly identical to those of the trialkoxysilane compounds, and both gave a much more stable attachment to the semiconductor compared with their cyanoacrylic acid counterpart, as shown by desorption experiments.

Organosilatrane building blocks

Phenylsilatrane analogues containing reactive amino, bromo, boronic ester, and alkynyl functional groups for coupling reactions have been prepared. Pinacol boronic ester and ethynyl analogues were synthesized from 4-bromophenylsilatrane by palladium catal