20376-31-2Relevant articles and documents
sym-TRIAZINE DERIVATIVES. 9. REACTION OF sym-TRIAZINES CONTAINING TRICHLOROMETHYL AND ETHOXYCARBONYL GROUPS WITH PHENYLHYDRAZINE
Alekseeva, N. V.,Turchin, K. F.,Anisimova, O. S.,Sheinker, Yu. N.,Yakhontov, L. N.
, p. 1375 - 1383 (2007/10/02)
Using the example of the reaction of 1,3,5-triazines simultaneously containing trichloromethyl and ethoxycarbonyl substituents with phenylhydrazine, it was shown that the presence of even one ester group leads to ring transformation.Depending on the numbe
Oligomerization of Trichloroacetonitrile (TCA) by Metal Salts
Suematsu, Kazumi
, p. 291 - 294 (2007/10/02)
A CN bond was found to transform into a C=N bond under such a mild conditions as to mix trichloroacetonitrile, metal salts and methanol at 20 deg C.Ni(II) and Co(II) gave dimeric ring complexes and Mn(II) gave amidine, aminotriazine and brown powder.The aminotriazine was isolated as unstable liquid which spontaneously transformed into the crystal.A trimer structure was proposed for the liquid.In anhydrous systems, any oligomerization did not occur, so water was concluded to participate in the initiation.Keywords - trichloroacetonitrile; metal salt; methanol; nitrile; imino bond; dimeric ring complex; amidine; aminotriazine; trimer