20414-99-7

Basic information

• Product Name: Benzene, (3-methyl-1,3-pentadienyl)-, (E,E)-
• CAS NO: 20414-99-7
• Molecular Formula: C12H14
• Molecular Weight: 158.243
• Mol File: 20414-99-7.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Benzene, (3-methyl-1,3-pentadienyl)-, (E,E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, (3-methyl-1,3-pentadienyl)-, (E,E)-(20414-99-7)
• EPA Substance Registry System: Benzene, (3-methyl-1,3-pentadienyl)-, (E,E)-(20414-99-7)

Safety Data

• Hazardous Substances Data: 20414-99-7(Hazardous Substances Data)

Upstream product

• 108-86-1 bromobenzene 
• 2787-43-1 (3E)-3-methylpenta-1,3-diene 
• 497-03-0 2-methylbut-2-enal 
• 1100-88-5 benzyltriphenylphosphonium chloride 
• 42599-24-6 E-styryl iodide 
• 28944-85-6 1-methyl-(Z)-propenyllithium 
• 867-13-0 diethoxyphosphoryl-acetic acid ethyl ester 
• 104722-55-6 3-Methyl-4-phenylamino-pent-1-en-3-ol 
• 4549-74-0 3-methyl-1,3-pentadiene 
• 75927-49-0 pinacol vinylboronate 
• 100-42-5 styrene 
• 3017-68-3 (Z)-2-Bromo-2-butene 
• 104722-33-0 N-acetyl, N-phenyl methyl-3 phenyl-5 amino-2 pentene-3 E 
• 110-91-8 morpholine 

Downstream Products

• 1557277-99-2 1-(5-phenylfuran-3-yl)ethanol 

Relevant articles and documents

Ligand-Free Iron-Catalyzed Carbon(sp2)-Carbon(sp2) Cross-Coupling of Alkenyllithium with Vinyl Halides

An efficient ligand-free iron-catalyzed cross-coupling reaction involving alkenyllithium and vinyl iodides was developed to form diene species in moderate to good yields. This new iron-catalyzed cross-coupling reaction provides a mild, inexpensive, and environmentally friendly avenue toward synthesis of diversified diene derivatives.

Chemoselective construction of substituted conjugated dienes using an olefin cross-metathesis protocol

(Chemical Equation Presented) Various substituted conjugated dienes have been made by olefin cross-metathesis. Using either electronic or steric "protection," one of the olefins of the conjugated diene was deactivated relative to the other for cross-metathesis. The reactions proceed with very high chemoselectivity and, when steric deactivation is used, very high diastereoselectivity.

Regioselective 1,4-addition of ammonia to 1-arylalka-1,3-dienes and 1-aryl-4-phenylbuta-1,3-dienes by photoinduced electron transfer

The photoamination of 1-arylalka-1,3-dienes 1a-f and 1-aryl-4-phenylbuta-1,3-dienes 1g-k with NH3 in the presence of p-dicyanobenzene (DCB) gives 4-amino-1-arylalk-2-enes 2a-f and 1-amino-1,4-diarylbut-2-enes 2g-k, respectively. The photoamination proceeds by nucleophilic addition of NH3 to the cation radicals of 1+. generated by photoinduced electron transfer to DCB. The regiochemistry of 2 is related to the distribution of the positive charge in 1+. calculated by the PM3-UHF/RHF method, the stability of the aminated radicals formed by the addition of NH3 to 1+. and the stability of the aminated anion formed by the reduction of the aminated radicals by DCB-.. The stabilities of these intermediates are estimated by the calculation of the heat of formation by the PM3-UHF/RHF method. Distributions of the positive charge in 1+. and the stabilities of the aminated anion show a good agreement with the product analysis.