2050-94-4Relevant articles and documents
A high yielding, one-pot synthesis of dialkyl carbonates from alcohols using Mitsunobu's reagent
Chaturvedi, Devdutt,Mishra, Nisha,Mishra, Virendra
, p. 5043 - 5045 (2007)
A Mitsunobu-based protocol has been developed for the synthesis of symmetrical and unsymmetrical dialkylcarbonates from a variety of primary, secondary and tertiary alcohols using gaseous carbon dioxide, in good to excellent yields. This protocol is mild and efficient compared to other reported methods.
Method for synthesizing organic carbonate from carbon dioxide, alcohol and brominated alkane under mild conditions
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Paragraph 0016-0017; 0018-0020; 0023-0024, (2020/06/02)
The invention discloses a method for synthesizing organic carbonate from carbon dioxide, alcohol and brominated alkane under mild conditions, belonging to the field of chemical synthesis. According tothe method, carbon dioxide, alcohol and brominated alkane are used as raw materials, 1,8-diazabicycloundec-7-ene (DBU) is used as an activating agent, and acetonitrile is used as a solvent to preparethe organic carbonate. The target product, namely the organic carbonate with excellent yield can be obtained under optimized reaction conditions. The method is mild in reaction conditions, simple andconvenient to operate and high in yield, and is an excellent system for preparing the organic carbonate.
CARBONATE DERIVATIVE PRODUCTION METHOD
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Paragraph 0135-0136; 0151-0152, (2020/04/09)
The objective of the present invention is to provide a method for producing a carbonate derivative in a safe and efficient manner. The method for producing a carbonate derivative according to the present invention is characterized in comprising irradiating light on a composition containing a C1-4 halogenated hydrocarbon having one or more kinds of halogen atoms selected from the group consisting of a chlorine atom, a bromine atom and an iodine atom, a nucleophilic functional group-containing compound and the specific base in the presence of oxygen.
Method for preparing dialkyl carbonate by alcoholysis of urea
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Paragraph 0047, (2018/09/08)
The invention relates to a method for preparing dialkyl carbonate by alcoholysis of urea, belonging to the field of chemical synthesis. More specifically, the invention relates to preparation of dialkyl carbonate. The method comprises the following step: subjecting urea and alkyl monohydric alcohol to a reflux reaction under stirring for 6 to 30 hours under the condition of normal pressure or reduced pressure at a reaction temperature of 70 to 150 DEG C by using one or more selected from the group consisting of metal magnesium, calcium, aluminum, chromium, manganese, iron, cobalt, nickel, copper or zinc as a main catalyst and one or more compounds containing donor atom nitrogen, phosphorus, oxygen or sulfur as an auxiliary catalyst so as to prepare the dialkyl carbonate. The preparation method provided by the invention has the following advantages: the dialkyl carbonate is prepared with high selectivity and high yield at a low reaction temperature under the condition of normal pressureor reduced pressure; simple operation, high safety and low cost are achieved in the processing process; and good industrial application prospects are obtained.