205259-72-9

Basic information

• Product Name: rhodium(III) tetrakis(4-tolyl)porphyrin chloride
• Synonyms: rhodium(III) tetrakis(4-tolyl)porphyrin chloride
• CAS NO: 205259-72-9
• Molecular Weight: 807.199
• Mol File: 205259-72-9.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: rhodium(III) tetrakis(4-tolyl)porphyrin chloride(CAS DataBase Reference)
• NIST Chemistry Reference: rhodium(III) tetrakis(4-tolyl)porphyrin chloride(205259-72-9)
• EPA Substance Registry System: rhodium(III) tetrakis(4-tolyl)porphyrin chloride(205259-72-9)

Safety Data

• Hazardous Substances Data: 205259-72-9(Hazardous Substances Data)

Upstream product

• 14527-51-6 5,10,15,20-tetra(p-tolyl)porphyrin 
• 108-90-7 chlorobenzene 
• 100-47-0 benzonitrile 

Downstream Products

• 103533-61-5 (5,10,15,20-tetrakis-4-tolylporphyrinato)(methyl)rhodium(III) 
• 1391996-58-9 Rh(tetra-p-tolylporphyrinato)(4-tert-butylphenyl) 
• 1391996-54-5 Rh(tetra-p-tolylporphyrinato)(4-chlorophenyl) 
• 1391996-60-3 5,10,15,20-tetra(p-tolyl)porphyrinato-rhodium(III)-p-fluorophenyl 
• 1391996-56-7 5,10,15,20-tetra(p-tolyl)porphyrinatorhodium(III)-p-nitro-phenyl 
• 911206-97-8 5,10,15,20-tetra(p-tolyl)porphyrinato-rhodium(III)-phenyl 
• 1391996-50-1 Rh(tetra-p-tolylporphyrinato)(4-methoxyphenyl) 
• 930573-95-8 (5,10,15,20-tetratolylporphyrinato)(4-tolyl)rhodium(III) 
• 1207742-32-2 rhodium(III)(5,10,15,20-tetratolylporphyrinato dianion)Bn(4-Cl) 
• 930574-04-2 rhodium(III) tetrakis(4-tolyl)porphyrin benzyl-d7 
• 930573-96-9 (5,10,15,20-tetratolylporphyrinato)(3-tolyl)rhodium(III) 
• 874299-61-3 (benzyl)(5,10,15,20-tetrakis-4-tolylporphyrinato)rhodium(III) 
• 1207742-35-5 rhodium(III)(5,10,15,20-tetratolylporphyrinato dianion)Bn(2-CH₃) 
• 1207742-34-4 (3-CH₃C₆H₄CH₂)rhodium(III) tetrakis(4-tolyl)porphyrin 

Relevant articles and documents

Aryl carbon-chlorine (Ar-Cl) and aryl carbon-fluorine (Ar-F) bond cleavages by rhodium porphyrins

Aryl carbon-chlorine (Ar-Cl) bond cleavage has been achieved with rhodium(III) tetrakis-4-tolylporphyrin chloride (Rh(ttp)Cl) to give Rh(ttp)Ar. For 4-chlorofluorobenzene, the aryl carbon-fluorine (Ar-F) bond cleavage competes with the Ar-Cl bond cleavage. Mechanistic investigations show that the Ar-Cl bond cleavage goes through metalloradical ipso-substitution mechanism, while the Ar-F bond cleavage goes through nucleophilic aromatic substitution. The selectivity of the Ar-F or Ar-Cl bond cleavage can be controlled by tuning the temperature and substrate concentration.

Effects of p-substituents on electrochemical CO oxidation by Rh porphyrin-based catalysts

Electrochemical CO oxidation by several carbon-supported rhodium tetraphenylporphyrins with systematically varied meso-substituents was investigated. A quantitative analysis revealed that the p-substituents on the meso-phenyl groups significantly affected CO oxidation activity. The electrocatalytic reaction was characterized in detail based on the spectroscopic and X-ray structural results as well as electrochemical analyses. The difference in the activity among Rh pophyrins is discussed in terms of the properties of p-substituents along with a proposed reaction mechanism. Rhodium tetrakis(4-carboxyphenyl)porphyrin (Rh(TCPP)), which exhibited the highest activity among the porphyrins tested, oxidized CO at a high rate at much lower potentials (2 oxidation activity, in contrast to Pt-based catalysts.

Synthesis of rhodium porphyrin aryls via intermolecular arene carbon-hydrogen bond activation

(meta-Cyanophenyl) rhodium porphyrins have been synthesized from the selective activation of a meta carbon-hydrogen bond of PhCN via the reaction of RhCl3 with porphyrins in refluxing PhCN.