20541-48-4

Basic information

• Product Name: Diselenide, bis(4-bromophenyl)
• Synonyms: di-p-bromophenyl diselenide;(4,4'-dibromodiphenyl) diselenide;bis(p-bromophenyl) diselenide;di(4-bromophenyl)diselenide;bis(4-bromophenyl) diselenide;1,2-bis(4-bromophenyl)diselane
• CAS NO: 20541-48-4
• Molecular Formula: C12H8Br2Se2
• Molecular Weight: 469.924
• Mol File: 20541-48-4.mol
• Article Data: 34

Chemical Properties

• CAS DataBase Reference: Diselenide, bis(4-bromophenyl)(CAS DataBase Reference)
• NIST Chemistry Reference: Diselenide, bis(4-bromophenyl)(20541-48-4)
• EPA Substance Registry System: Diselenide, bis(4-bromophenyl)(20541-48-4)

Safety Data

• Hazardous Substances Data: 20541-48-4(Hazardous Substances Data)

Upstream product

• 38927-01-4 benzeneselenenyl tribromide 
• 32449-46-0 1-bromo-4-selenocyanatobenzene 
• 57878-24-7 4-bromo-benzeneselenenyl bromide 
• 5467-74-3 4-Bromophenylboronic acid 
• 589-87-7 1,4-bromoiodobenzene 
• 17893-52-6 (4-bromo-phenylselanyl)-acetic acid 
• 856129-25-4 ethyl-dibromo-(4-bromo-phenyl)-λ⁴-selane 
• 856074-02-7 ethyl-(4-bromo-phenyl)-selenide 
• 62350-86-1 tribromo-(4-bromo-phenyl)-λ⁴-selane 
• 106-37-6 1.4-dibromobenzene 
• 2028-85-5 (4-bromophenyl)diazonium chloride 
• 127-09-3 sodium acetate 
• 18620-02-5 (4-bromophenyl)magnesium bromide 
• 17333-82-3 4-bromo-benzenediazonium ion 

Downstream Products

• 727739-21-1 Cp₂TiCl(SeC₆H₄Br-p) 
• 727739-18-6 Cp₂Ti(SeC₆H₄Br-p)2 
• 1290541-88-6 2-(p-bromophenylseleno)mesitylene 
• 40400-25-7 (4-bromophenyl)(methyl)selane 

Relevant articles and documents

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Enhancing the Potential of Miniature-Scale DNA-Compatible Radical Reactions via an Electron Donor-Acceptor Complex and a Reversible Adsorption to Solid Support Strategy

DNA-encoded library (DEL) technology is a powerful tool in the discovery of bioactive probe molecules and drug leads. Mostly, the success in DEL technology stems from the molecular diversity of the chemical libraries. However, the construction of DELs has been restricted by the idiosyncratic needs and the required low concentration (～1 mM or less) of the library intermediate. Here, we report visible-light-promoted on-DNA radical coupling reactions via an electron donor-acceptor (EDA) complex and a reversible adsorption to solid support (RASS) strategy. This protocol provides a unique solution to the challenges of increasing the reactivity of highly diluted DNA substrates and reducing the residues of heavy metals from photocatalysts. A series of on-DNA indole sulfone and selenide derivatives were obtained with good to quantitative conversions. It is anticipated that these mild-condition on-DNA radical reactions will significantly improve the chemical diversity of DELs and find widespread utility to DEL construction.

Blue light-promoted radical sulfoximido-chalcogenization of aliphatic and aromatic alkenes

A transition metal-free synthesis ofN-(arylthio/seleno)ethyl sulfoxidminesviablue light-promoted radical sulfoximido-chalcogenization of aliphatic and aromatic alkenes was developed. The sulfoximidation process demonstrated high chemoselectivity and allowed a broad substrate scope, completing the sulfoximido-chalcogenization of alkenes in good yields.

FeCl3-catalyzed three-component aryl-selenylation of alkenes

FeCl3-catalyzed three-component aryl-selenylation of alkenes with good to excellent yields has been disclosed. This method is characterized by synthesis of complicated products in a single-step reaction, simple operation and readily available commercially reagents. Finally, a reasonable mechanism of FeCl3-catalyzed aryl-selenylation is proposed.