205808-71-5Relevant articles and documents
Photoisomerization of all-cis-1,6-diphenyl-1,3,5-hexatriene in the solid state and in solution: A simultaneous three-bond twist process
Saltiel, Jack,Papadimitriou, Dimitrios,Krishna, Tallapragada S. R.,Huang, Zhen-Nian,Krishnamoorthy, Govindarahan,Laohhasurayotin, Somchoke,Clark, Ronald J.
scheme or table, p. 8082 - 8085 (2010/01/16)
Disrotatory bicycle pedals: Irradiation of the title compound in the solid state gives the all-trans isomer directly in a crystal-to-crystal reaction. This threefold cis-trans photoisomerization is proposed to proceed by a two-stage mechanism that is consistent with two simultaneous bicyclepedal processes occurring in disrotatory fashion about the central bond.
Stereoselective Synthesis of Substituted 1,3,5-Hexatrienes from Diallylic Sulfones
Cao, Xiao-Ping,Chan, Tze-Lock,Chow, Hak-Fun,Tu, Jingren
, p. 1297 - 1300 (2007/10/02)
Substituted 1,3,5-hexatrienes 7 can be prepared in excellent yields and with good stereoselectivity from diallylic sulfones 6 employing a modified Ramberg-Baecklund reaction.