2059-43-0

Basic information

• Product Name: 4-allyl-4-methylcyclohexa-2,5-dien-1-one
• Synonyms: 4-allyl-4-methylcyclohexa-2,5-dien-1-one
• CAS NO: 2059-43-0
• Molecular Weight: 148.205
• Mol File: 2059-43-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 4-allyl-4-methylcyclohexa-2,5-dien-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 4-allyl-4-methylcyclohexa-2,5-dien-1-one(2059-43-0)
• EPA Substance Registry System: 4-allyl-4-methylcyclohexa-2,5-dien-1-one(2059-43-0)

Safety Data

• Hazardous Substances Data: 2059-43-0(Hazardous Substances Data)

Upstream product

• 4519-36-2 (4-methylbenzyl)-trimethylammonium chloride 
• 34921-09-0 diethyl (4-methylbenzyl) phosphate 
• 1131688-12-4 C₁₆H₂₈OSi₂ 
• 106-44-5 p-cresol 
• 106-95-6 allyl bromide 

Downstream Products

• 41516-23-8 3-allyl-4-methylphenol 
• 6628-06-4 2-allyl-4-methylphenol 
• 32853-54-6 C₁₇H₂₀N₂O₂S 
• 19689-33-9 6-allyl-6-methyl-cyclohexa-2,4-dien-1-one 

Relevant articles and documents

Pd-catalyzed C4-Dearomative Allylation of Benzyl Ammoniums with Allyltributylstannane

A dearomative C4-allylation of benzyl ammoniums with allyltributylstannane by a palladium catalysis is described. A triarylphosphine-ligated palladium catalyst, which is capable of cleaving benzylic CN bonds, realized facile dearomative reactions with C4 selectivity. Combined with precedented C2- A nd C3-selective functionalizations of benzyl amine derivatives, the present reaction can provide a new synthetic option for the synthesis of multi-substituted alicyclic compounds as well as aromatic compounds.

On the way to an oxidative Hosomi-Sakurai reaction

An oxidative allylation process mediated by a hypervalent iodine reagent has been performed on polysubstituted phenols. This reaction, occurring in useful to good yields, leads to a rapid access to dienones containing a quaternary carbon center. Georg Thieme Verlag Stuttgart.