2060-91-5Relevant articles and documents
Steady-state photolysis of dimesitylbis(trimethylsilyl)germane
Hurni, Krysten L.,Baines, Kim M.
, p. 668 - 674 (2008/09/19)
The photolysis of dimesitylbis(trimethylsilyl)germane (3) in hexanes or THF, at low temperature, has been investigated as a potential method for the preparative-scale synthesis of tetramesityldigermene (5). A product mixture, consisting of hexamethyldisilane, mesitylene, 2-trimethylsilylmesitylene (7), a new germacyclobutene (8), and an unidentified polymer, was obtained. No evidence for the formation of tetramesityldigermene (5) was observed.
Stable 2-Vinylsiliranes
Zhang,Conlin
, p. 4272 - 4278 (2007/10/02)
Seven 2-vinyl-1,1-dimesitylsiliranes, stable at room temperature over months, have been synthesized from the addition of dimesitylsilylene to 2,3-dimethylbutadiene, 2-methylbutadiene, trans,trans-2,4-hexadiene, cis,cis-2,4-hexadiene, and cis,trans-2,4-hex