206125-07-7

Basic information

• Product Name: ((1R,2S,5R,6S)-2-Benzyloxy-3,7-dioxa-bicyclo[4.1.0]hept-5-yloxy)-triisopropyl-silane
• Synonyms: ((1R,2S,5R,6S)-2-Benzyloxy-3,7-dioxa-bicyclo[4.1.0]hept-5-yloxy)-triisopropyl-silane
• CAS NO: 206125-07-7
• Molecular Weight: 378.584
• Mol File: 206125-07-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: ((1R,2S,5R,6S)-2-Benzyloxy-3,7-dioxa-bicyclo[4.1.0]hept-5-yloxy)-triisopropyl-silane(CAS DataBase Reference)
• NIST Chemistry Reference: ((1R,2S,5R,6S)-2-Benzyloxy-3,7-dioxa-bicyclo[4.1.0]hept-5-yloxy)-triisopropyl-silane(206125-07-7)
• EPA Substance Registry System: ((1R,2S,5R,6S)-2-Benzyloxy-3,7-dioxa-bicyclo[4.1.0]hept-5-yloxy)-triisopropyl-silane(206125-07-7)

Safety Data

• Hazardous Substances Data: 206125-07-7(Hazardous Substances Data)

Upstream product

• 13154-24-0 triisopropylsilyl chloride 
• 61134-24-5 Benzyl 2,3-anhydro-α-D-ribopyranoside 

Downstream Products

• 206124-71-2 (2S,3S,4S,5R)-2-Benzyloxy-3-methyl-5-triisopropylsilanyloxy-tetrahydro-pyran-4-ol 

Relevant articles and documents

Endocyclic cleavage of glycosides. VI. Substituent effects of the alkylative endocyclic cleavage of glycosides

A number of pentopyranoside derivatives were treated with Me3Al in order to investigate the influence of structural parameters on the methyl group transfer in the endocyclic alkylative cleavage reaction of these substrates. A cyclic CH ··· O hydrogen bonded model is suggested as an intermediate, which is used to explain the stereoselectivities for different substrates. In several, cases the diastereoselectivities were better than 9:1.