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20643-22-5

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  • Bicyclo[4.2.0]octa-1,3,5-trien-7-one,3,5-dimethyl-,2-(3,5-dimethylbicyclo[4.2.0]octa-1,3,5-trien-7-ylidene)hydrazone

    Cas No: 20643-22-5

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  • Bicyclo[4.2.0]octa-1,3,5-trien-7-one,3,5-dimethyl-,2-(3,5-dimethylbicyclo[4.2.0]octa-1,3,5-trien-7-ylidene)hydrazone cas 20643-22-5

    Cas No: 20643-22-5

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20643-22-5 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 20643-22-5 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 2,0,6,4 and 3 respectively; the second part has 2 digits, 2 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 20643-22:
(7*2)+(6*0)+(5*6)+(4*4)+(3*3)+(2*2)+(1*2)=75
75 % 10 = 5
So 20643-22-5 is a valid CAS Registry Number.

20643-22-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name (Z)-N-[(Z)-(3,5-dimethyl-7-bicyclo[4.2.0]octa-1,3,5-trienylidene)amino]-3,5-dimethylbicyclo[4.2.0]octa-1,3,5-trien-7-imine

1.2 Other means of identification

Product number -
Other names 4,6-Dimethylbenzocyclobutenone azine

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:20643-22-5 SDS

20643-22-5Upstream product

20643-22-5Downstream Products

20643-22-5Relevant articles and documents

Benzocyclobutenylidene-Cycloadditions, Reactivity, and Multiplicity

Duerr, Heinz,Nickels, Helmut,Pacala, Luba A.,Jones, Maitland

, p. 973 - 980 (2007/10/02)

EHT and CNDO/2 calculations on benzocyclobutenylidene (6) are described.Flash pyrolysis of the tosylhydrazone salt 7 affords benzocyclobutene and o-xylene in low yield, along with the formal syn and anti carbene dimers 13 and 14.Condensed-phase reactions were achieved by photolysis of the salt 15.Benzocyclobutenylidene (6) gave rise to the formal carbene dimers 17 and 18.Insertion of carbene 6 into the carbon-hydrogen bonds of 2,3-dimethylbutane produced the benzocyclobutenes 20 and 21 (insertion ratio tertiary:primary = 9:1).Cycloaddition of 6 to olefins gave only spirohexene derivatives 22.Multiplicity studies of 6 with cis or trans olefins indicated that 6 undergoes cycloaddition in a stereospecific manner.Competition experiments using dienes and monoolefins implicate an equilibrium between singlet and triplet 6.Further competition experiments with styrene/para-substituted styrene pairs demonstrated that 6 reacts faster with electron-poor styrenes.Possible explanations for this apparent anomaly are discussed.

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